Molybdenum pentachloride

Base Information

• Chemical Name: Molybdenum pentachloride
• CAS No.: 10241-05-1
• Molecular Formula: MoCl5
• Molecular Weight: 273.205
• Hs Code.: 28273985
• European Community (EC) Number: 233-575-3
• UN Number: 2508
• Wikipedia: Molybdenum(V) chloride
• Wikidata: Q2615924
• Mol file: 10241-05-1.mol

Synonyms:MoCl3;MoCl5;molybdenum chloride;molybdenum pentachloride;molybdenum trichloride;molybdenum(III) chloride

Chemical Property of Molybdenum pentachloride

Chemical Property:

• Appearance/Colour: dark blue to black crystals
• Vapor Pressure: 1.75 mm Hg ( 25 °C)
• Melting Point: 194 °C(lit.)
• Boiling Point: 268 °C(lit.)
• PSA: 0.00000
• Density: 2.928 g/mL at 25 °C(lit.)
• LogP: 3.44750
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in dry ether, dry alcohol, organic solvents and chlorina
• Water Solubility.: soluble in dry ether and dry alcohol, in other organic solvents [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 274.746717
• Heavy Atom Count: 6
• Complexity: 37.1
• Transport DOT Label: Corrosive

Purity/Quality:

98% or more ^*data from raw suppliers

Molybdenum(V) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 29-34-48/20/22-40
• Safety Statements: 26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: Cl[Mo](Cl)(Cl)(Cl)Cl
• Physical Properties: Greenish-black monoclinic crystals or dark red as liquid or vapor; paramagnetic; hygroscopic; critical temperature 577°C; critical volume 369 cm3/mol; soluble in dry ether, dry alcohol and many other organic solvents; reacts with water.
• Uses: Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl. Molybdenum pentachloride (MoCl5) is used as a brazing and soldering flux and to make fire-retardant resins. Molybdenum pentachloride MoCl5 is used as a catalyst for several polymerization reactions involving olefins, vinyl monomers, trioxane, ethylene, vinylcyclohexane, cyclopentene, and butadiene.

Technology Process of Molybdenum pentachloride

There total 34 articles about Molybdenum pentachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

chlorine (7782-50-5) + molybdenum (7439-98-7) → molybdenum(V) chloride (10241-05-1)

Guidance literature:

dry chlorine was passed over finely divided molebdenum at 300°C; sublimation;

Reference yield:

chlorine (7782-50-5) + molybdenum (7439-98-7) → molybdenum(V) chloride (10241-05-1) + molybdenum(IV) chloride (13320-71-3)

Guidance literature:

In neat (no solvent); introduction of Cl2-gas (8-9 Torr/20 min/1.8 l/h) through purified (90min/H2 stream/1000°C) Mo powder (860 - 1160°C);; extraction of MoCl5 (CCl4); extraction MoCl4 (diethylether or water); further extraction (ethanol or water);;

Reference yield:

tetrachloromethane (56-23-5) + molybdenum(IV) oxide → molybdenum(V) chloride (10241-05-1) + molybdenum(IV) chloride (13320-71-3)

Guidance literature:

With pyrographite; mass ratio MoO2:C = 5:1; mixt. heated at 300°C in a flow of N2 loaded with CCl4; absence of moisture and oxygen; further by-product: Mo oxide chloride; removal of MoCl5 and Mo oxide chloride by vac. distn.;

upstream raw materials:

perfluoropropylene

sulfur dichloride

tetrachlorosilane

tetrachloromethane

Downstream raw materials:

molybdenum(VI) tetrachloride oxide

dioxomolybdenum(VI) dichloride

molybdenum(IV) chloride

molybdenum

Refernces

• 1、 Brisdon, Alan K.,Graham, John T.,Hope, Eric G.,Jenkins, Delyth M.,Levason, William,Ogden, J. Steven. "Spectroscopic Studies on Matrix-isolated Molybdenum Pentachloride". . p. 1529 - 1532. Retrieved 1990.
• 2、 Pap, I. S.,Mink, G.,Auroux, A.,Karmazsin, E.. "". . p. 247 - 258. Retrieved 1994.
• 3、 Schaefer, H.. "". . p. 53 - 55. Retrieved 1963.
• 4、 Beck,Mueller-Buschbaum,Wolf. "On tetrachlorophosphonium chlorometallates of rhenium and molybdenum: Syntheses, crystal structures, and magnetism of [PCl4]2[Re2Cl10] and [PCl4]3[ReCl6]2, and the magnetic properties of [PCl4]2[Mo2Cl10]". . p. 975 - 981. Retrieved 2008/10/08.