Bis(4-glycidyloxyphenyl)methane

Base Information

• Chemical Name: Bis(4-glycidyloxyphenyl)methane
• CAS No.: 2095-03-6
• Molecular Formula: C19H20 O4
• Molecular Weight: 312.365
• European Community (EC) Number: 218-257-4
• UNII: V3625OQU1K
• DSSTox Substance ID: DTXSID4044872
• Nikkaji Number: J298.690F
• Wikidata: Q27291479
• ChEMBL ID: CHEMBL3182674
• Mol file: 2095-03-6.mol

Synonyms:BFDGE cpd;bisphenol F diglycidyl ether

Chemical Property of Bis(4-glycidyloxyphenyl)methane

Chemical Property:

• Melting Point: −15 °C(lit.)
• Refractive Index: n20/D 1.579(lit.)
• Boiling Point: 474°Cat760mmHg
• Flash Point: 161.8°C
• PSA: 43.52000
• Density: 1.213g/cm³
• LogP: 2.83260
• Storage Temp.: 2-8°C
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 312.13615911
• Heavy Atom Count: 23
• Complexity: 324

Purity/Quality:

98%,99%, ^*data from raw suppliers

BisphenolFDiglycidylEther ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N
• Statements: 36/38-43-50/53-36/37/38
• Safety Statements: 37/39-61-60-36/37-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1C(O1)COC2=CC=C(C=C2)CC3=CC=C(C=C3)OCC4CO4
• Uses: Bisphenol F Diglycidyl Ether is an novalac glycidyl ether (NOGE). Bisphenol F Diglycidyl Ether is found in resin used as coatings for food cans. Bisphenol F Diglycidyl Ether is a toxic conatminant wit h strict limitations on the amount allowed in food products.

Technology Process of Bis(4-glycidyloxyphenyl)methane

There total 3 articles about Bis(4-glycidyloxyphenyl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bis-(4-hydroxyphenyl)methane (620-92-8) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → bis[p-(2,3-epoxypropoxy)phenyl]methane (2095-03-6)

Guidance literature:

With tetrabutylammomium bromide; potassium hydroxide; at 20 ℃; for 12h;

Reference yield:

bis(4-(allyloxy)phenyl)methane → bisphenol F monogycidyl ether + bis[p-(2,3-epoxypropoxy)phenyl]methane (2095-03-6)

Guidance literature:

With dihydrogen peroxide; sodium tungstate monohydrate; Aminomethylphosphonic acid; methyl tri-n-octyl ammonium hydrogen sulfate; In water; at 80 - 85 ℃; for 2h;

Reference yield:

bis-(4-hydroxyphenyl)methane (620-92-8) → bisphenol F monogycidyl ether + bis[p-(2,3-epoxypropoxy)phenyl]methane (2095-03-6)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / triphenylphosphine; 5%-palladium/activated carbon / isopropyl alcohol; water / 8 h / 85 °C / Inert atmosphere

2: dihydrogen peroxide / methyl tri-n-octyl ammonium hydrogen sulfate; Aminomethylphosphonic acid; sodium tungstate monohydrate / water / 2 h / 80 - 85 °C

With dihydrogen peroxide; potassium carbonate; sodium tungstate monohydrate; Aminomethylphosphonic acid; 5%-palladium/activated carbon; triphenylphosphine; methyl tri-n-octyl ammonium hydrogen sulfate; In water; isopropyl alcohol;

upstream raw materials:

bis-(4-hydroxyphenyl)methane

epichlorohydrin

Refernces

• 1、 -. "Preparation method of bisphenol F 2222,dihydroxypropyl (2 -chloro -1 - propyl) diethyl ether". Paragraph 0024-0026. . Retrieved 2021/11/21.