N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine

Base Information

• Chemical Name: N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine
• CAS No.: 33329-35-0
• Deprecated CAS: 859630-21-0,2283364-53-2
• Molecular Formula: C15H36N4
• Molecular Weight: 272.478
• Hs Code.: 2921290000
• European Community (EC) Number: 251-459-0
• DSSTox Substance ID: DTXSID5052703
• Nikkaji Number: J40.098J
• Wikidata: Q72445170
• Mol file: 33329-35-0.mol

Synonyms:33329-35-0;N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine;N,N-BIS[3-(DIMETHYLAMINO)PROPYL]-N',N'-DIMETHYLPROPANE-1,3-DIAMINE;EINECS 251-459-0;1,3-Propanediamine, N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethyl-;N',N'-bis[3-(dimethylamino)propyl]-N,N-dimethylpropane-1,3-diamine;C15H36N4;EC 251-459-0;N,N-Bis(3-(dimethylamino)propyl)-N',N'-dimethyl-1,3-propanediamine;1,3-Propanediamine, N,N-bis(3-(dimethylamino)propyl)-N',N'-dimethyl-;1,3-Propanediamine, N1,N1-bis(3-(dimethylamino)propyl)-N3,N3-dimethyl-;Tris-(dimethylaminopropyl)amine;N,N-Bis(3-(dimethylamino)propyl)-N',N'-dimethylpropane-1,3-diamine;Tris[3-(dimethylamino)propyl]amine;SCHEMBL15620;DTXSID5052703;Tris(N,N-dimethylaminopropyl)amine;tris-(3-dimethylaminopropyl) amine;MFCD00190091;AKOS015850716;BS-17020;CS-0151283;A875326;J-019145;N\',N\'-bis[3-(dimethylamino)propyl]-N,N-dimethylpropane-1,3-diamine

Chemical Property of N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine

Chemical Property:

• Vapor Pressure: 1.333hPa at 10℃
• Boiling Point: 297.7 °C at 760 mmHg
• PKA: 10.05±0.28(Predicted)
• Flash Point: 112.5 °C
• PSA: 12.96000
• Density: 0.892 g/cm3
• LogP: 1.14350
• Storage Temp.: 2-8°C
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• Water Solubility.: 54.99g/L at 25℃
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 272.29399717
• Heavy Atom Count: 19
• Complexity: 159

Purity/Quality:

99% ^*data from raw suppliers

Tris(N,N-dimethylaminopropyl)amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)CCCN(CCCN(C)C)CCCN(C)C
• Uses: Tris(N,N-dimethylaminopropyl)amine has been used in the synthesis of nickel(II) and cobalt(II) complexes with the propylene-bridged tripod ligand tris(3-dimethylaminopropyl)amine (donor set N4).

Technology Process of N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine

There total 3 articles about N1,N1-Bis(3-(Dimethylamino)propyl)-N3,N3-dimethylpropane-1,3-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-amino-3-(dimethylamino)propane (109-55-7) + 3-dimethylaminopropiononitrile (1738-25-6) → N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethylpropane-1,3-diamine (33329-35-0) + N,N-bis-(3-dimethylaminopropyl)amine (6711-48-4,86003-72-7)

Guidance literature:

With Pd/γ-Al2O3; hydrogen; In toluene; at 80 ℃; for 4h; under 30003 Torr; Concentration; Autoclave;

DOI:10.1002/bkcs.11401

Reference yield:

1-amino-3-(dimethylamino)propane (109-55-7) → N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethylpropane-1,3-diamine (33329-35-0) + N,N-bis-(3-dimethylaminopropyl)amine (6711-48-4,86003-72-7)

Guidance literature:

With hydrogen; at 100 - 200 ℃; under 0 - 15001.5 Torr; Product distribution / selectivity;

Reference yield:

→ N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethylpropane-1,3-diamine (33329-35-0)

Guidance literature:

entspr. Chlorid, Dimethylamin;

DOI:10.1039/j19710002024

upstream raw materials:

1-amino-3-(dimethylamino)propane

3-dimethylaminopropiononitrile

Refernces

• 1、 Lin, Chenhui,Wang, Bowei,Guo, Haotian,Chen, Ligong,Yan, Xilong. "Selective synthesis of N,N-bis(3-dimethylaminopropyl)amine over Pd/γ-Al2O3". . p. 391 - 396. Retrieved 2018.