platinum hexafluoride

Base Information

• Chemical Name: platinum hexafluoride
• CAS No.: 13693-05-5
• Molecular Formula: F6Pt
• Molecular Weight: 309.07
• Mol file: 13693-05-5.mol

Synonyms:Platinumfluoride (PtF6) (6CI,7CI,8CI); Platinum hexafluoride; Platinum hexafluoride(PtF6)

Chemical Property of platinum hexafluoride

Chemical Property:

• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 61.3°C
• Boiling Point: 19.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -17.97850

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Physical Properties: Dark-red octahedral crystals; volatile and unstable; density 3.83g/cm3; melts at 61.3°C; vaporizes at 69.14°C; reacts violently with water.
• Uses: Platinum hexafluoride does not have many commercial applications. It is used as a strong oxidizing agent and can oxidize oxygen from the air. It is used in research. Platinum hexafluoride forms compounds with molecular oxygen and xenon, [O2+][PtF6 –] and XePtF6 , respectively.

Technology Process of platinum hexafluoride

There total 2 articles about platinum hexafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

fluorine (7782-41-4) + platinum (7440-06-4) → platinum hexafluoride (13693-05-5)

Guidance literature:

In neat (no solvent); electrically heating Pt wire under F2 at -196°C;

DOI:10.1021/ic052029f

Reference yield:

platinum (7440-06-4) → platinum hexafluoride (13693-05-5)

Guidance literature:

With F₂; In neat (no solvent); large excess F2 (Pt:F2=1:15), 200°C, 15 atm, 5 h;

Reference yield:

uranium(IV) tetrafluoride (10049-14-6) + platinum hexafluoride (13693-05-5) → uranium hexafluoride (7783-81-5)

Guidance literature:

heating;

upstream raw materials:

fluorine

platinum

Downstream raw materials:

chlorine pentafluoride

ClF₂⁽¹⁺⁾*PtF₆^(1-)=ClF₃*PtF₅

krypton difluoride

krypton tetrafluoride

Refernces

• 1、 Holloway, John H.,Stanger, Gillian,Hope, Eric G.,Levason, William,Ogden, J. Steven. "Spectroscopic Studies on the Hexafluorides of Rhenium, Osmium, Iridium, and Platinum isolated in Low-temperature Matrices". . p. 1341 - 1346. Retrieved 2007/10/02.