m-Tolyl phosphorodichloridate

Base Information

• Chemical Name: m-Tolyl phosphorodichloridate
• CAS No.: 940-18-1
• Molecular Formula: C7H7Cl2O2P
• Molecular Weight: 225.011
• NSC Number: 66505
• DSSTox Substance ID: DTXSID50290095
• Nikkaji Number: J32.903G
• Wikidata: Q82027684
• Mol file: 940-18-1.mol

Synonyms:m-Tolyl phosphorodichloridate;940-18-1;NSC66505;1-dichlorophosphoryloxy-3-methylbenzene;m-tolyl dichlorophosphate;SCHEMBL11556570;DTXSID50290095;3-methylphenyl phosphorodichloridate;NSC-66505;STL280377;AKOS016025210

Chemical Property of m-Tolyl phosphorodichloridate

Chemical Property:

• Vapor Pressure: 0.014mmHg at 25°C
• Boiling Point: 266.7°C at 760 mmHg
• Flash Point: 131.1°C
• Density: 1.405g/cm³
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 223.9560718
• Heavy Atom Count: 12
• Complexity: 192

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=CC=C1)OP(=O)(Cl)Cl

Technology Process of m-Tolyl phosphorodichloridate

There total 2 articles about m-Tolyl phosphorodichloridate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methyl-phenol (108-39-4) → m-Tolyl dichlorophosphate (940-18-1)

Guidance literature:

With triethylamine; trichlorophosphate; In benzene; Heating;

Reference yield:

3-methyl-phenol (108-39-4) → bis(3-methylphenyl) chlorophosphate (6630-14-4) + m-Tolyl dichlorophosphate (940-18-1)

Guidance literature:

With aluminium trichloride; trichlorophosphate;

DOI:10.1021/ja01536a052

Reference yield: 76.0%

2-hydroxy-5-chloro-aniline (95-85-2) + m-Tolyl dichlorophosphate (940-18-1) → C19H15Cl2N2O3P (125790-29-6)

Guidance literature:

With triethylamine; In benzene; Heating;

upstream raw materials:

3-methyl-phenol

Downstream raw materials:

denitrofenitrooxon

2-m-tolyloxy-[1,3,2]diazaphosphinane 2-oxide

2-m-Tolyloxy-3H-[1,3,2]oxazaphospholo[4,5-b]pyridine 2-oxide

C₁₉H₁₇N₂O₃P

Refernces

• 1、 Chan, Li Yan,Cheong, Lilian,Kim, Sunggak. "Pd(II)-catalyzed ortho-arylation of aryl phosphates and aryl hydrogen phosphates with diaryliodonium triflates". supporting information. p. 2186 - 2189. Retrieved 2013/06/05.
• 2、 Stephen Babu,Anasuyamma,Venugopal,Naga Raju,Suresh Reddy. "Syntheses and spectral characterization of 2-aryloxy - 5,5′- bis(bromomethyl)-1,3,2P-dioxaphosphorinane 2-oxides". . p. 1248 - 1251. Retrieved 2007/10/03.