POLY(ALLYLAMINE)

Base Information

• Chemical Name: POLY(ALLYLAMINE)
• CAS No.: 30551-89-4
• Molecular Formula: C₃H₇N
• Molecular Weight: 57.0953
• Mol file: 30551-89-4.mol

Synonyms:2-Propenaminehomopolymer; Allylamine homopolymer; Allylamine polymer; Allylamine, polymers;PAA 01; PAA 03; PAA 05; PAA 08; PAA 10C; PAA 10L; PAA 15; PAA 15C; PAA 1LV; PAA1LV40C; PAA 25; PAA 25 (allyl polymer); PAA-H; PAA-L; PAA-L (polyamine); PAS-F5000; Poly(2-propen-1-amine); Poly(allylamine)

Chemical Property of POLY(ALLYLAMINE)

Chemical Property:

• Appearance/Colour: liquid
• Melting Point: -88oC
• Refractive Index: n20/D 1.383
• Boiling Point: 55-58ºC
• PSA: 26.02000
• Density: 1.02 g/mL at 25 °C
• LogP: 0.83140

Purity/Quality:

98%,99%, ^*data from raw suppliers

Poly(allylamine) solution average Mw ~17,000, 20 wt. % in H2O ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Soluble in water, lower alcohols, ethylene glycol and formamide.

Technology Process of POLY(ALLYLAMINE)

There total 84 articles about POLY(ALLYLAMINE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Propargylamine (2450-71-7) → 1-amino-2-propene (107-11-9,30551-89-4)

Guidance literature:

With 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride; diethoxymethylane; sodium triethylborohydride; In neat (no solvent); at -78 - 40 ℃; for 1h;

DOI:10.1021/acscatal.6b02272

Reference yield: 87.0%

3-amino-1,2-epoxypropane (5689-75-8) → 1-amino-2-propene (107-11-9,30551-89-4)

Guidance literature:

With sodium iodide; tin(ll) chloride; In ethanol; for 0.05h; Reflux; Green chemistry;

DOI:10.1055/s-0034-1378821

Reference yield: 82.0%

N-allyl-N'-phenylhydrazine (71056-34-3) → 1-amino-2-propene (107-11-9,30551-89-4)

Guidance literature:

With titanium(III) chloride; water; In tetrahydrofuran; pH=10; Reflux; Alkaline aq. solution; Inert atmosphere;

DOI:10.1039/c1ob05328k

upstream raw materials:

allyl iodid

2,3-dibromopropan-1-amine

hexamethylenetetramine

allyl bromide

Downstream raw materials:

2-(allylamino)ethanol

2,2′-(prop-2-en-1-ylimino)diethanol

allyl-(1,1-dioxo-tetrahydro-1λ⁶-[3]thienyl)-amine

N,N'-diallyl-phthalamide

Refernces

• 1、 -. "METHOD FOR PRODUCING PRIMARY AMINES". Paragraph 0047; 0050. . Retrieved 2019/08/27.
• 2、 Shahsavari, Shahien,McNamara, Chase,Sylvester, Mark,Bromley, Emily,Joslin, Savannah,Lu, Bao-Yuan,Fang, Shiyue. "An amine protecting group deprotectable under nearly neutral oxidative conditions". . p. 1750 - 1757. Retrieved 2018/08/21.