sodium m-toluidinomethanesulphonate

Base Information

• Chemical Name: sodium m-toluidinomethanesulphonate
• CAS No.: 6274-20-0
• Molecular Formula: C8H11 N O3 S . Na
• Molecular Weight: 223.228
• Mol file: 6274-20-0.mol

Synonyms:Methanesulfonicacid, [(3-methylphenyl)amino]-, monosodium salt (9CI); Methanesulfonic acid,m-toluidino-, monosodium salt (8CI)

Chemical Property of sodium m-toluidinomethanesulphonate

Chemical Property:

• PSA: 74.78000
• LogP: 2.40600

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium m-toluidinomethanesulphonate

There total 1 articles about sodium m-toluidinomethanesulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.8%

sodium formaldehyde bisulfite (870-72-4) + 1-amino-3-methylbenzene (108-44-1) → sodium m-tolylamino-N-methanesulfonate (6274-20-0)

Guidance literature:

In ethanol; water; at 20 - 100 ℃; for 5h;

Reference yield:

sodium m-tolylamino-N-methanesulfonate (6274-20-0) + 4-fluoroaniline (371-40-4) → C13H12FN3 (1352059-92-7)

Guidance literature:

4-fluoroaniline; With hydrogenchloride; sodium nitrite; In water; at 0 ℃; for 1h;

sodium m-tolylamino-N-methanesulfonate; With aminosulfonic acid; sodium carbonate; In water; at 0 - 5 ℃; for 4h; pH=9;

Reference yield:

sodium m-tolylamino-N-methanesulfonate (6274-20-0) → C15H16N4O

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydrogenchloride; sodium nitrite / water; methanol / 1 h / -5 - 5 °C

1.2: 2 h / 0 - 20 °C

2.1: potassium carbonate / water / 4 h / 80 °C

With hydrogenchloride; potassium carbonate; sodium nitrite; In methanol; water;

upstream raw materials:

sodium formaldehyde bisulfite

1-amino-3-methylbenzene

Downstream raw materials:

C₁₃H₁₂FN₃

4,4'-diamino-2-methylazobenzene

Refernces