1-Chlorophenanthrene

Base Information

• Chemical Name: 1-Chlorophenanthrene
• CAS No.: 832-70-2
• Molecular Formula: C14H9Cl
• Molecular Weight: 212.678
• DSSTox Substance ID: DTXSID50984700
• Nikkaji Number: J1.945.995K
• Wikidata: Q82971995
• Mol file: 832-70-2.mol

Synonyms:1-Chlorophenanthrene;Phenanthrene, chloro-;Phenanthrene, 1-chloro-;66214-77-5;832-70-2;Chlorphenanthren;SCHEMBL476875;DTXSID50984700

Chemical Property of 1-Chlorophenanthrene

Chemical Property:

• Vapor Pressure: 2.42E-05mmHg at 25°C
• Boiling Point: 370.1°C at 760 mmHg
• Flash Point: 179.2°C
• Density: 1.253g/cm³
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 212.0392780
• Heavy Atom Count: 15
• Complexity: 225

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C=CC=C3Cl

Technology Process of 1-Chlorophenanthrene

There total 2 articles about 1-Chlorophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polyvinyl chloride, free of additives, powder form → 2-chloronaphthalene (91-58-7) + 9-chlorophenanthrene (947-72-8) + 1-chlorophenanthrene (832-70-2) + 1-Chloronaphthalene (90-13-1)

Guidance literature:

With air; at 600 ℃; Further Variations:; Temperatures; Product distribution; UV-irradiation;

DOI:10.1016/S0045-6535(03)00507-1

Reference yield:

C16H12ClNO3S → 1-chlorophenanthrene (832-70-2) + 1-chloro-2-(2-phenylethynyl)benzene (10271-57-5)

Guidance literature:

With morpholine; In toluene; at 20 ℃; for 1.8h; Overall yield = 70 %; regioselective reaction; UV-irradiation;

DOI:10.1039/c7ra00193b

Refernces

• 1、 Chen, Ming,Zhao, Xinxin,Yang, Chao,Wang, Yanpei,Xia, Wujiong. "Further insight into the photochemical behavior of 3-aryl-N-(arylsulfonyl)propiolamides: tunable synthetic route to phenanthrenes". . p. 12022 - 12026. Retrieved 2017/03/01.