dimethyl naphthalene-1,2-dicarboxylate

Base Information

• Chemical Name: dimethyl naphthalene-1,2-dicarboxylate
• CAS No.: 10060-32-9
• Molecular Formula: C14H12O4
• Molecular Weight: 244.247
• DSSTox Substance ID: DTXSID40574053
• Nikkaji Number: J47.551C
• Wikidata: Q63409035
• Mol file: 10060-32-9.mol

Synonyms:1,2-naphthalenedicarboxylic acid dimethyl ester;naphthalene-1,2-dicarboxylic acid dimethyl ester;dimethyl naphthalene dicarboxylate;dimethyl 1,2-naphthalenedicarboxylate;Naphthalenedicarboxylic acid,dimethyl ester;Naphthalin-1,2-dicarbonsaeure-dimethylester;dimethylnaphtalene-2,3-dicarboxylate;

Chemical Property of dimethyl naphthalene-1,2-dicarboxylate

Chemical Property:

• Vapor Pressure: 5.98E-05mmHg at 25°C
• Boiling Point: 345.9oC at 760 mmHg
• Flash Point: 170.8oC
• PSA: 52.60000
• Density: 1.225g/cm3
• LogP: 2.41300
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 244.07355886
• Heavy Atom Count: 18
• Complexity: 326

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C1=C(C2=CC=CC=C2C=C1)C(=O)OC

Technology Process of dimethyl naphthalene-1,2-dicarboxylate

There total 9 articles about dimethyl naphthalene-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + dimethyl acetylenedicarboxylate (762-42-5) → dimethyl 1,2-naphthalenedicarboxylate (10060-32-9)

Guidance literature:

With Fe_3.3Ni_0.01(fumarate)*(Cl)y; In acetonitrile; at 100 ℃; for 20h; Catalytic behavior; Sealed tube; Green chemistry;

DOI:10.1039/d0gc00619j

Reference yield:

1,2-Dihydronaphthalene (447-53-0) + dimethyl acetylenedicarboxylate (762-42-5) → ethene (74-85-1) + dimethyl 1,2-naphthalenedicarboxylate (10060-32-9)

Guidance literature:

Reference yield:

2aH-7-Thia-cyclobuta[a]indene-1,7a-dicarboxylic acid dimethyl ester (31739-28-3) → dimethyl 1,2-naphthalenedicarboxylate (10060-32-9)

Guidance literature:

at 240 ℃; for 0.25h;

DOI:10.1021/jo00823a021

upstream raw materials:

benzothiophene-1,1-dioxide

dimethyl acetylenedicarboxylate

methanol

1,2-naphthalenedicarboxylic anhydride

Downstream raw materials:

4,5-Benzindan

Refernces

• 1、 Zimmerman,H.E.,Grunewald,G.L.. "". . p. 1434 - 1436. Retrieved 1964.
• 2、 Abbasnia, Masoumeh,Bahmani, Mona,Sheykhan, Mehdi,Taghizadeh, Parvaneh. "MOFs come up to scratch: An environmentally benign route to oxidative [4 + 2] cycloaddition on maleimides solely: Via MOFs in water". . p. 3216 - 3228. Retrieved 2020.