Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester

Base Information

• Chemical Name: Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester
• CAS No.: 102804-62-6
• Molecular Formula: C11H15NO2
• Molecular Weight: 193.246
• Mol file: 102804-62-6.mol

Synonyms:

Chemical Property of Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester

There total 1 articles about Cyclohexanecarboxylic acid, 1-cyano-, 2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1,5-dibromo-pentane (111-24-0) + allyl cyanoacetate (13361-32-5) → Allyl 1-cyanocyclohexanecarboxylate (102804-62-6)

Guidance literature:

With potassium carbonate; In acetone; Heating;

DOI:10.1055/s-1987-28145

Reference yield: 81.0%

Allyl 1-cyanocyclohexanecarboxylate (102804-62-6) → cyclohexane carbonitrile (766-05-2) + cyclohex-1-enecarbonitrile (1855-63-6)

Guidance literature:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenylphosphine; In various solvent(s); for 1h; Yields of byproduct given; Heating;

DOI:10.1055/s-1987-28145

Reference yield: 81.0%

Allyl 1-cyanocyclohexanecarboxylate (102804-62-6) → cyclohex-1-enecarbonitrile (1855-63-6)

Guidance literature:

With triphenylphosphine; Pd₂(dibenzylideneacetone)2*CHCl₃; In various solvent(s); for 3h; Heating;

DOI:10.1039/c39860000118

upstream raw materials:

1,5-dibromo-pentane

allyl cyanoacetate

Downstream raw materials:

cyclohexane carbonitrile

cyclohex-1-enecarbonitrile

Refernces