Tris(tetrabutylammonium) hexakis(cyano-C)ferrate

Base Information

• Chemical Name: Tris(tetrabutylammonium) hexakis(cyano-C)ferrate
• CAS No.: 14589-06-1
• Molecular Formula: C54H108FeN9
• Molecular Weight: 939.359
• European Community (EC) Number: 238-630-5
• Mol file: 14589-06-1.mol

Synonyms:14589-06-1;Tris(tetrabutylammonium) hexakis(cyano-C)ferrate;EINECS 238-630-5;iron(3+);tetrabutylazanium;hexacyanide;TETRABUTYLAMMONIUMHEXACYANOFERRATE(III);Tris(tetrabutylammonium)hexacyanoferrate(III);Tetrabutylammoniumhexacyanoferrat(III);Tetrabutylammonium hexacyanoferrate(III);Tris[tetrabutylammonium]hexakis(cyano-c)ferrate

Chemical Property of Tris(tetrabutylammonium) hexakis(cyano-C)ferrate

Chemical Property:

• Melting Point: 262-263 °C (dec.)
• PSA: 142.74000
• LogP: 15.10900
• Solubility.: H2O: 0.1 g/mL, clear
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 36
• Exact Mass: 938.807705
• Heavy Atom Count: 64
• Complexity: 243

Purity/Quality:

98%Min ^*data from raw suppliers

TRIS(TETRABUTYLAMMONIUM)HEXACYANOFERRATE 98.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+3]

Technology Process of Tris(tetrabutylammonium) hexakis(cyano-C)ferrate

There total 1 articles about Tris(tetrabutylammonium) hexakis(cyano-C)ferrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrabutyl-ammonium chloride (1112-67-0) + potassium hexacyanoferrate(III) → tetra-n-butyl ammonium hexacyanoferrate(III) (14589-06-1)

Guidance literature:

In dichloromethane; water; K3Fe(CN)6 and Bu4NCl (molar ratio: 1:3) addn. to CH2Cl2/H2O (1:1); stirred 2h; organic layer collected; evapn.; dried; addn. of diethyl ether; stirred several hours; boiled 5-10 min; filtered hot; repeated; removing Bu4NCl in ether soln.; residue dried in oven at 100°C;

Reference yield: 71.0%

tetra-n-butyl ammonium hexacyanoferrate(III) (14589-06-1) + [Co(II)(1,2-bis(diphenylphosphino)ethane)2(H2O)][BF4]2 → ([Co(II)(1,2-bis(diphenylphosphino)ethane)2]2[Fe(III)(CN)6])(BF4)

Guidance literature:

In acetonitrile; under anaerobic conditions soln. (TBA)3(Fe(CN)6) in MeCN was added to soln. Co(II) complex in MeCN, left to stand for 3 days; ppt. was filtered in air and washed with MeOH; elem. anal.;

DOI:10.1021/ic901681e

Reference yield: 30.0%

methanol (67-56-1) + tetra-n-butyl ammonium hexacyanoferrate(III) (14589-06-1) + [Mn(acacen)(H2O)2](PF6) + C12H24O6*C6H6FN*H(1+) → C12H24O6*C6H6FN*C12H22N2O2(2-)*CH4O*2H(1+)*6CN(1-)*Fe(3+)*Mn(3+)

Guidance literature:

methanol; tetra-n-butyl ammonium hexacyanoferrate(III); C₁₂H₂₄O₆*C₆H₆FN*H⁽¹⁺⁾; for 1h;

[Mn(acacen)(H₂O)₂](PF₆);

DOI:10.1021/acs.inorgchem.8b00983

upstream raw materials:

tetrabutyl-ammonium chloride

Downstream raw materials:

Prussian blue

Refernces