1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene

Base Information

• Chemical Name: 1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene
• CAS No.: 336-19-6
• Molecular Formula: C6Cl2F8
• Molecular Weight: 294.959
• Hs Code.: 2903890090
• European Community (EC) Number: 206-408-7
• UNII: 8J478Z2BJ5
• DSSTox Substance ID: DTXSID30187297
• Nikkaji Number: J193.781B
• Wikidata: Q81985507
• Mol file: 336-19-6.mol

Synonyms:336-19-6;1,2-Dichlorooctafluorocyclohex-1-ene;1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene;1,2-Dichlorooctafluorocyclohexene;1,2-Dichloroperfluorocyclohexene;Octafluorodichlorocyclohexene;Cyclohexene, 1,2-dichlorooctafluoro-;BRN 1886511;1,2-Dichlorooctafluorocyclohexene-1;EINECS 206-408-7;1,2-dichloro-3,3,4,4,5,5,6,6-octafluorocyclohex-1-ene;Cyclohexene, 1,2-dichloro-3,3,4,4,5,5,6,6-octafluoro-;8J478Z2BJ5;4-05-00-00231 (Beilstein Handbook Reference);C6Cl2F8;Cinnamyl3-aminocrotonate;UNII-8J478Z2BJ5;C6-Cl2-F8;SCHEMBL1995973;DTXSID30187297;1,2-di-chlorooctafluorocyclohexene;MFCD00039466;1,2-dichlorooctafluoro-1-cyclohexene;AKOS015850014;LS-57505;CS-0451234;FT-0606386;A821877;1,2-Dichloro-3,3,4,4,5,5,6,6-octafluoro-1-cyclohexene;1,2-bis(chloranyl)-3,3,4,4,5,5,6,6-octakis(fluoranyl)cyclohexene

Chemical Property of 1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene

Chemical Property:

• Vapor Pressure: 26.7mmHg at 25°C
• Melting Point: -70°C
• Refractive Index: 1.375
• Boiling Point: 111.5 °C at 760 mmHg
• Flash Point: 33.6 °C
• PSA: 0.00000
• Density: 1.74 g/cm³
• LogP: 4.23040
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 293.9249307
• Heavy Atom Count: 16
• Complexity: 324

Purity/Quality:

99% ^*data from raw suppliers

1,2-Dichlorooctafluorocyclohexene-1 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 20/21/22
• Safety Statements: 23-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(C(C(C1(F)F)(F)F)(F)F)(F)F)Cl)Cl

Technology Process of 1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene

There total 3 articles about 1,2-Dichloro-3,3,4,4,5,5,6,6-octafluorocyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexachlorobenzene (118-74-1,67471-27-6) → 1,2-dichloro-3,3,4,4,5,5,6,6-octafluoro-cyclohexene (336-19-6)

Guidance literature:

With antimony pentafluoride; at 100 - 200 ℃;

DOI:10.1021/ie50447a629 DOI:10.1021/ie50447a639

Reference yield:

1-chloro-2,3,3,4,4,5,5,6,6-nonafluorocyclohexene (15145-21-8) → 1,2-dichloro-3,3,4,4,5,5,6,6-octafluoro-cyclohexene (336-19-6) + decafluorocyclohex-1-ene (355-75-9)

Guidance literature:

With antimony pentafluoride; at 150 ℃; for 5h; Product distribution;

Reference yield:

→ 1,2-dichloro-3,3,4,4,5,5,6,6-octafluoro-cyclohexene (336-19-6)

Guidance literature:

Chlor-pentafluor-benzol, SbF5;

upstream raw materials:

hexachlorobenzene

1-chloro-2,3,3,4,4,5,5,6,6-nonafluorocyclohexene

Downstream raw materials:

3,3,4,4,5,5,6,6-Octafluor-cyclohex-1-en-1,2-diphosphonsaeure-1,2-tetraaethylester

Octafluor-1,2-bis-phenylmercapto-cyclohexen

C₂₄H₁₄F₈S₂

Refernces

• 1、 McBee,Lindgren,Ligett. "-". . p. 378,379. Retrieved 1947.
• 2、 Bardin, V. V.,Avramenko, A. A.,Petrov, V. A.,Krasil'nikov, V. A.,Karelin, A. I.,et al. "REACTION OF POLYFLUORINATED CYCLOALKANES WITH VANADIUM, ANTIMONY, AND NIOBIUM PENTAFLUORIDES". . p. 536 - 540. Retrieved 2007/10/02.