Glucose 6-(hydrogen sulfate)

Base Information

• Chemical Name: Glucose 6-(hydrogen sulfate)
• CAS No.: 3803-84-7
• Molecular Formula: C6H12O9S
• Molecular Weight: 260.222
• Hs Code.: 2914400090
• DSSTox Substance ID: DTXSID40191446
• Wikidata: Q27102087
• Mol file: 3803-84-7.mol

Synonyms:glucose 6-(hydrogen sulfate);glucose 6-(hydrogen sulfate), monopotassium salt, (D)-isomer;glucose 6-(hydrogen sulfate), monosodium salt, (D)-isomer;glucose sulfate;potassium glucose 6-O-sulfate

Chemical Property of Glucose 6-(hydrogen sulfate)

Chemical Property:

• Refractive Index: 1.599
• PSA: 169.97000
• Density: 1.841 g/cm³
• LogP: -2.47090
• XLogP3: -3.8
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 7
• Exact Mass: 260.02020313
• Heavy Atom Count: 16
• Complexity: 307

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(C(C(C(C=O)O)O)O)O)OS(=O)(=O)O
• Isomeric SMILES: C([C@H]([C@H]([C@@H]([C@H](C=O)O)O)O)O)OS(=O)(=O)O

Technology Process of Glucose 6-(hydrogen sulfate)

There total 9 articles about Glucose 6-(hydrogen sulfate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ D-glucose-6-sulfate (3803-84-7,56614-20-1)

Guidance literature:

With acetic acid;

DOI:10.1038/183109a0

Reference yield:

D-glucose (50-99-7) → D-glucose-6-sulfate (3803-84-7,56614-20-1)

Guidance literature:

With pyridine; chlorosulphuric acid; nicht einheitliches Praeparat, in dem O⁶-Sulfo-D-glucose als Hauptbestandteil vorgelegen hat, ist erhalten worden;

DOI:10.1042/bj0830455 DOI:10.1021/jo01063a064

Reference yield:

pyridine-SO3 complex (42824-16-8) + D-glucose (50-99-7) → D-glucose-6-sulfate (3803-84-7,56614-20-1)

Guidance literature:

With pyridine; nicht einheitliches Praeparat, in dem O⁶-Sulfo-D-glucose als Hauptbestandteil vorgelegen hat, ist erhalten worden;

DOI:10.1042/bj0830455 DOI:10.1021/jo01063a064

upstream raw materials:

pyridine-SO₃ complex

D-glucose

water

O¹,O²,O³,O⁴-Tetraacetyl-O⁶-sulfo-β-D-glucopyranose

Downstream raw materials:

D-glucose

Refernces

• 1、 LLOYD. "Fractionation of the products of the direct sulphation of monosaccharides on anion-exchange resin.". . p. 455 - 460. Retrieved 2007/11/09.