Triethylmethylammonium bromide

Base Information

• Chemical Name: Triethylmethylammonium bromide
• CAS No.: 2700-16-5
• Molecular Formula: C7H18 N . Br
• Molecular Weight: 196.131
• Hs Code.: 2923900090
• European Community (EC) Number: 220-282-0
• DSSTox Substance ID: DTXSID50949778
• Mol file: 2700-16-5.mol

Synonyms:Triethylmethylammonium bromide;2700-16-5;N,N-Diethyl-N-methylethanaminium bromide;Methyltriethylammonium bromide;triethyl(methyl)azanium;bromide;EINECS 220-282-0;triethyl(methyl)azanium,bromide;SCHEMBL235582;triethyl-methyl-azanium bromide;DTXSID50949778;METHYLTRIETHYLAMMONIUMBROMIDE;AMY13795;N,N-Diethyl-N-methylethanaminiumbromide;AS-78191;Triethylmethylammonium bromide, >=99.0%;FT-0628342;E85298

Chemical Property of Triethylmethylammonium bromide

Chemical Property:

• Melting Point: 307 ºC (dec.)
• PSA: 0.00000
• LogP: -1.50330
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 195.06226
• Heavy Atom Count: 9
• Complexity: 47.1

Purity/Quality:

99% ^*data from raw suppliers

N,N-Diethyl-N-methylethanaminium bromide 95+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[N+](C)(CC)CC.[Br-]

Technology Process of Triethylmethylammonium bromide

There total 4 articles about Triethylmethylammonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

triethylamine hydrobromide (636-70-4) + carbonic acid dimethyl ester (616-38-6) → N,N,N-triethyl-N-methylammonium bromide (2700-16-5)

Guidance literature:

With 1-ethyl-3-methylimidazolium bromide; at 169.84 ℃; for 8h;

DOI:10.1002/adsc.200600451

Reference yield: 94.0%

phenylselenomethyltriethylammonium bromide → N,N,N-triethyl-N-methylammonium bromide (2700-16-5)

Guidance literature:

With tert-Amyl alcohol; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; for 0.25h; Heating; Irradiation;

DOI:10.1021/jo9813538

Reference yield:

methyl bromide (74-83-9) + triethylamine (121-44-8) → N,N,N-triethyl-N-methylammonium bromide (2700-16-5)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; at 20 - 30 ℃; for 15h; Inert atmosphere;

upstream raw materials:

methyl bromide

trimethylamine

triethylamine hydrobromide

carbonic acid dimethyl ester

Downstream raw materials:

methane

ethane

ethene

triethylamine

Refernces

• 1、 -. "Method of producing oxyborate Tetracyanobicyclo (by machine translation)". Paragraph 0075. . Retrieved 2016/12/26.
• 2、 Della, Ernest W.,Smith, Paul A.. "Synthesis of bridgehead nitrogen heterocycles via cyclization of α- ammonio 5-hexenyl radicals". . p. 1798 - 1806. Retrieved 2007/10/03.