Chloroaluminum(2+);2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene

Base Information

• Chemical Name: Chloroaluminum(2+);2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene
• CAS No.: 14154-42-8
• Molecular Formula: C32H16AlClN8
• Molecular Weight: 574.967
• Hs Code.: 29339900
• Mol file: 14154-42-8.mol

Synonyms:

Chemical Property of Chloroaluminum(2+);2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene

Chemical Property:

• Appearance/Colour: COA
• Melting Point: >300 °C(lit.)
• PSA: 84.02000
• LogP: 2.15390
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 574.1001836
• Heavy Atom Count: 42
• Complexity: 711

Purity/Quality:

99% ^*data from raw suppliers

AluminumPhthalocyanineChloride(TechnicalGrade) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 22-24/25-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=C5C=CC=CC5=C([N-]4)N=C6C7=CC=CC=C7C(=N6)N=C8C9=CC=CC=C9C(=N8)N=C2[N-]3.[Al+2]Cl
• Uses: Aluminum phthalocyanine chloride (CAS# 14154-42-8) is a fluorescent organometallic compound, able to generate reactive oxygen species. The photophysical properties of aluminum phthalocyanine chloride has allowed for the preparation of thin film organic photodetectors for indirect X-ray detection.

Technology Process of Chloroaluminum(2+);2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene

There total 13 articles about Chloroaluminum(2+);2,11,20,29,37,38-hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.26%

aluminum (III) chloride (7446-70-0,7784-13-6) + urea (57-13-6) + phthalonitrile (91-15-6) → chloroaluminum phthalocyanine (14154-42-8,62905-77-5)

Guidance literature:

With ammonium molybdate; at 200 ℃; for 12h;

Reference yield: 98.4%

aluminum (III) chloride (7446-70-0,7784-13-6) + phthalonitrile (91-15-6) → chloroaluminum phthalocyanine (14154-42-8)

Guidance literature:

With ammonium chloride; at 200 ℃; for 10.5h; Reagent/catalyst; Concentration;

Reference yield: 92.5%

aluminum (III) chloride (7446-70-0,7784-13-6) + phthalonitrile (91-15-6) → chloroaluminum phthalocyanine (14154-42-8,62905-77-5)

Guidance literature:

With 1-Chloronaphthalene; In water; acetone; toluene; at 70 - 240 ℃; for 10h;

upstream raw materials:

aluminum (III) chloride

phthalonitrile

quinoline

aluminium trichloride

Downstream raw materials:

hydroxyaluminum(III) phthalocyanine

Refernces

• 1、 Basova, Tamara V.,Kiselev, Vitaly G.,Plyashkevich, Vladimir A.,Cheblakov, Pavel B.,Latteyer, Florian,Peisert, Heiko,Chassè, Thomas. "Orientation and morphology of chloroaluminum phthalocyanine films grown by vapor deposition: Electrical field-induced molecular alignment". . p. 40 - 47. Retrieved 2011.
• 2、 Krier,Azim-Araghi. "The influence of NO2 on the conductivity of chloro-aluminium phthalocyanine thin films". . p. 711 - 716. Retrieved 1997.
• 3、 Raboui, Hasan,Al-Amar, Mohammad,Abdelrahman, Ahmed I.,Bender, Timothy P.. "Axially phenoxylated aluminum phthalocyanines and their application in organic photovoltaic cells". . p. 45731 - 45739. Retrieved 2015.
• 4、 -. "COMPOUND, PHOTOSENSITIVE RESIN COMPOSITION COMPRISING SAME, PHOTORESIST, COLOR FILTER AND DISPLAY DEVICE". Paragraph 0218-0221. . Retrieved 2021/01/01.
• 5、 -. "Phthalocyanine pigment". Paragraph 0070; 0071. . Retrieved 2018/09/02.