CID 10271322

Base Information

• Chemical Name: CID 10271322
• CAS No.: 14220-64-5
• Molecular Formula: C₁₄H₁₀Cl₂N₂Pd
• Molecular Weight: 383.573
• Hs Code.: 28439090
• European Community (EC) Number: 238-085-3
• Wikipedia: Bis(benzonitrile)palladium_dichloride
• Mol file: 14220-64-5.mol

Synonyms:14220-64-5;Bis(benzonitrile)palladium chloride;benzonitrile;palladium(2+);dichloride;Bis(benzonitrile)dichloropalladium(II);C14H10Cl2N2Pd;C14-H10-Cl2-N2-Pd;Dichlorobis(benzonitrile)palladium(II);AMY11856;AKOS015917605;LS-0005;B1668

Chemical Property of CID 10271322

Chemical Property:

• Appearance/Colour: yellow powder
• Vapor Pressure: 0.524mmHg at 25°C
• Melting Point: 131 °C(lit.)
• Boiling Point: 191.1 °C at 760 mmHg
• Flash Point: 71.7 °C
• PSA: 47.58000
• LogP: 4.49556
• Storage Temp.: Store below +30°C.
• Solubility.: Soluble in acetone, chloroform
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 381.92558
• Heavy Atom Count: 19
• Complexity: 103

Purity/Quality:

99% ^*data from raw suppliers

Bis(benzonitrile)palladium(II) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21-23/24/25
• Safety Statements: 22-24/25-23-45-36/37-27-20-9-4

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C#N.C1=CC=C(C=C1)C#N.[Cl-].[Cl-].[Pd+2]
• Uses: suzuki reaction Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine. Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.In cross-coupling reactions and α-O-glycosidation.Formal anti-Markovnikov hydroamination of terminal olefins

Technology Process of CID 10271322

There total 7 articles about CID 10271322 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

aqua regia + palladium (7440-05-3) + benzonitrile (100-47-0) → bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5)

Guidance literature:

aqua regia; palladium; at 100 ℃; for 1.5h;

benzonitrile; at 150 ℃; for 5h; Temperature;

Reference yield: 93.0%

benzonitrile (100-47-0) + palladium dichloride → bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5)

Guidance literature:

In benzonitrile; inert atmosphere; stirring at 100°C for 20 min; filtration, pptn. on addn. of petroleumether at room temp., washing (petroleum ether), drying in air;

DOI:10.1016/0020-1693(95)04995-9

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + palladium diacetate (3375-31-3) + benzonitrile (100-47-0) → bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5)

Guidance literature:

In water; at 90 ℃; for 0.5h;

DOI:10.1002/adsc.201800452

upstream raw materials:

benzonitrile

PdCl₂(P(C₆H₅)(2-C₆H₄Cl)2)2

hydrogenchloride

palladium diacetate

Downstream raw materials:

ferrocenecarboxaldehyde

Cl₂Pd(((C₆H₅)2P)2CHCH₂OC₄H₉)

(NC)2Pd((C₆H₅)2PCH₂P(C₆H₅)2)2

PdCl₂(CO)(benzonitrile)

Refernces

• 1、 Khairul, Wan M.,Wahab, Falynee Faha Abdul,Soh, Siti Kamilah Che,Shamsuddin, Mustaffa,Daud, Adibah Izzati. "Palladium(II)-pivaloyl thiourea complexes: Synthesis, characterisation and their catalytic activity in mild Sonogashira cross-coupling reaction". . . Retrieved 2020.
• 2、 Cypryk, Marek,Pospiech, Piotr,Strzelec, Krzysztof,Wasikowska, Karolina,Sobczak, Janusz W.. "Soluble polysiloxane-supported palladium catalysts for the Mizoroki-Heck reaction". . p. 30 - 38. Retrieved 2010.
• 3、 -. "Preparation method of bis (cyanobenzene) palladium dichloride". Paragraph 0011-0017. . Retrieved 2021/04/03.
• 4、 Lasri, Jamal,Pedras, Bruno,Haukka, Matti,Berberan-Santos, Mário N.. "Pt(II) and Pd(II)-assisted coupling of nitriles and 1,3-diiminoisoindoline: Synthesis and luminescence properties of (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) and Pd(II) complexes". . p. 195 - 202. Retrieved 2017/06/13.