3,4-diethylhex-3-ene

Base Information

• Chemical Name: 3,4-diethylhex-3-ene
• CAS No.: 868-46-2
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Mol file: 868-46-2.mol

Synonyms:tetraethylethene;3,4-diethyl-hex-3-ene;tetraethylethylene;Tetraaethylaethylen;3,4-Diaethyl-hex-3-en;3,4-Diethyl-3-hexene;

Chemical Property of 3,4-diethylhex-3-ene

Chemical Property:

• Vapor Pressure: 1.98mmHg at 25°C
• Boiling Point: 170.1°C at 760 mmHg
• Flash Point: 46.5°C
• PSA: 0.00000
• Density: 0.75g/cm³
• LogP: 3.92300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,4-diethylhex-3-ene

There total 5 articles about 3,4-diethylhex-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pentan-3-one (96-22-0) → 3,4-diethyl-3-hexene (868-46-2) + 2-pentanol (584-02-1) + 3,4-diethyl-hexane-3,4-diol (6931-71-1) + pentane (109-66-0,8031-35-4,9078-70-0)

Guidance literature:

With titanium tetrachloride; lithium; In tetrahydrofuran; at 20 ℃; for 10h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1002/anie.199723801

Reference yield:

pentan-3-one (96-22-0) → 3,4-diethyl-3-hexene (868-46-2) + (E)-pent-2-ene (646-04-8) + 2-pentanol (584-02-1) + 3,4-diethyl-hexane-3,4-diol (6931-71-1)

Guidance literature:

With titanium tetrachloride; lithium; In tetrahydrofuran; at 20 ℃; for 10h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1002/anie.199723801

Reference yield:

C10H20O2(2-)*2Li(1+) → 3,4-diethyl-3-hexene (868-46-2) + (E)-pent-2-ene (646-04-8) + 3,4-diethyl-hexane-3,4-diol (6931-71-1) + pentane (109-66-0,8031-35-4,9078-70-0)

Guidance literature:

With titanium tetrachloride; lithium; In tetrahydrofuran; at 20 ℃; for 10h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1002/anie.199723801

upstream raw materials:

diethyl sulfate

hex-3-yne

pentan-3-one

Downstream raw materials:

3,4-diethylhexane

Refernces

• 1、 Villiers, Claude,Ephritikhine, Michel. "New insights into the mechanism of the McMurry reaction". . p. 2380 - 2382. Retrieved 2007/10/03.