cis-4-Decenal

Base Information

• Chemical Name: cis-4-Decenal
• CAS No.: 30390-50-2
• Molecular Formula: C10H18 O
• Molecular Weight: 154.252
• Hs Code.: 2912190090
• European Community (EC) Number: 244-514-5
• UNII: 5R675PGU7K
• DSSTox Substance ID: DTXSID5041514
• Nikkaji Number: J225.408E
• Wikidata: Q27162280
• Metabolomics Workbench ID: 3542
• Mol file: 30390-50-2.mol

Synonyms:cis-4-Decenal;21662-09-9;(Z)-4-Decenal;(Z)-dec-4-enal;(4Z)-4-Decenal;cis-4-Decen-1-al;4Z-Decenal;(Z)-4-Decen-1-al;4-cis-Decenal;4-DECENAL, (Z)-;5R675PGU7K;4-Decenal, (4Z)-;DTXSID5041514;(4z)-dec-4-enal;4-DECENAL, CIS-;UNII-5R675PGU7K;SCHEMBL1255463;DTXCID3021514;(Z)-4-DECENAL [FCC];CHEBI:90056;CWRKZMLUDFBPAO-SREVYHEPSA-N;WAA66209;Tox21_300829;LMFA06000147;MFCD00007024;AKOS037621276;cis-4-Decenal, technical grade, 80%;NCGC00248186-01;NCGC00254733-01;cis-4-Decenal, >=93%, stabilized, FG;CAS-21662-09-9;J-014217;Q27162280

Chemical Property of cis-4-Decenal

Chemical Property:

• Melting Point: -16°C (estimate)
• Refractive Index: 1.4450
• Boiling Point: 200℃
• Flash Point: 81℃
• PSA: 17.07000
• Density: 0.835
• LogP: 3.10200
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 154.135765193
• Heavy Atom Count: 11
• Complexity: 105

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CCCC=O
• Isomeric SMILES: CCCCC/C=C\CCC=O

Technology Process of cis-4-Decenal

There total 12 articles about cis-4-Decenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1-dimethoxy-4Z-decene (68133-80-2) → (Z)-4-decenal (30390-50-2,65405-70-1,21662-09-9)

Guidance literature:

With hydrogenchloride; In acetone; for 4h; Ambient temperature;

Reference yield: 89.0%

(Z)-4-decen-1-ol (57074-37-0) → (Z)-4-decenal (30390-50-2,65405-70-1,21662-09-9)

Guidance literature:

(Z)-4-decen-1-ol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 2h; Inert atmosphere;

With triethylamine; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201300739

Reference yield:

trans,trans-2,4-decadienal (25152-84-5,65909-91-3) → (2E,4Z)-2,4-decadienal (25152-83-4,65909-91-3) + (Z)-4-decenal (30390-50-2,65405-70-1,21662-09-9) + benzaldehyde (100-52-7) + hexanal (66-25-1)

Guidance literature:

With L-lysine; at 125 ℃; for 0.333333h; Closed vial;

DOI:10.1021/jf104091p

upstream raw materials:

(Z)-4-decen-1-ol

1,1-dimethoxy-4Z-decene

1,1-dimethoxy-8-tosyloxy-(4Z)-octene

(Z)-4-decenoic acid ethyl ester

Downstream raw materials:

ethyl trans-2, cis-6-dodecadienoate

((E)-1-Benzenesulfonyl-dec-4-enyl)-carbamic acid benzyl ester

(4E,6E,10Z)-4,6,10-hexadecatrienyl acetate

(4E,6Z,10Z)-4,6,10-hexadecatrienyl acetate

Refernces

• 1、 Jiang, Ying,Sun, Bing,Fang, Wan-Yin,Qin, Hua-Li. "A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2". supporting information. p. 3190 - 3194. Retrieved 2019/05/21.
• 2、 Egger, Julian,Bretscher, Peter,Freigang, Stefan,Kopf, Manfred,Carreira, Erick M.. "Synthesis of epoxyisoprostanes: Effects in reducing secretion of pro-inflammatory cytokines IL-6 and IL-12". supporting information. p. 5382 - 5385. Retrieved 2013/06/26.