Campestanol

Base Information

• Chemical Name: Campestanol
• CAS No.: 474-60-2
• Molecular Formula: C28H50 O
• Molecular Weight: 402.704
• UNII: 5J08LF99N1
• DSSTox Substance ID: DTXSID3040988
• Nikkaji Number: J166.111F
• Wikipedia: Campestanol
• Wikidata: Q15410858
• Metabolomics Workbench ID: 34766
• Mol file: 474-60-2.mol

Synonyms:campestanol

Chemical Property of Campestanol

Chemical Property:

• Vapor Pressure: 1.87E-10mmHg at 25°C
• Boiling Point: 461.4°C at 760 mmHg
• Flash Point: 193°C
• PSA: 20.23000
• Density: 0.951g/cm³
• LogP: 7.71460
• XLogP3: 9.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 402.386166214
• Heavy Atom Count: 29
• Complexity: 569

Purity/Quality:

98%Min ^*data from raw suppliers

Campestanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C(C)CCC(C)C1CCC2C1(CCC3C2CCC4C3(CCC(C4)O)C)C
• Isomeric SMILES: C[C@H](CC[C@@H](C)C(C)C)[C@H]1CC[C@@H]2[C@@]1(CC[C@H]3[C@H]2CC[C@@H]4[C@@]3(CC[C@@H](C4)O)C)C
• Uses: A phytosterol Campestanol can be used as analyte in biological and analytical studies for the determination of 22 natural brassinosteroids in a minute sample of plant tissue by UHPLC-ESI-MS/MS.

Technology Process of Campestanol

There total 43 articles about Campestanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phytosterol → Stigmastanol (83-45-4) + campestanol (474-60-2)

Guidance literature:

With hydrogen; 5% Pd on alumina; In isopropyl alcohol; at 70 ℃; for 24h; under 3102.97 Torr;

Reference yield:

5β-lumistan-3β-ol (601-44-5) → 5β-lumistanol-(3α) (474-59-9,474-60-2,474-61-3,516-76-7,601-44-5,6538-02-9,17105-72-5,33947-18-1,35799-12-3,50298-91-4,58718-19-7,66036-55-3,70095-92-0,83861-56-7,96478-82-9,98463-66-2,103419-98-3,103419-99-4,106454-90-4,115458-67-8,115458-68-9,122087-74-5,122564-42-5,122564-43-6,122797-93-7,128050-56-6)

Guidance literature:

With ethanol; sodium ethanolate; at 200 ℃;

Reference yield:

5α,10α-ergostanol-(3β) (474-59-9) → 24βF-methyl-5α.10α-cholestanol-(3α) (474-59-9,474-60-2,474-61-3,516-76-7,601-44-5,6538-02-9,17105-72-5,33947-18-1,35799-12-3,50298-91-4,58718-19-7,66036-55-3,70095-92-0,83861-56-7,96478-82-9,98463-66-2,103419-98-3,103419-99-4,106454-90-4,115458-67-8,115458-68-9,122087-74-5,122564-42-5,122564-43-6,122797-93-7,128050-56-6)

Guidance literature:

With ethanol; sodium ethanolate; at 190 ℃;

DOI:10.1080/10473289.2002.10470843

upstream raw materials:

(10S)-3c-Acetoxy-10r.13c-dimethyl-17c-((1R:4R)-1.4.5-trimethyl-hexen-(2t)-yl)-(5ξH.9cH.14tH)-Δ⁷-tetradecahydro-1H-cyclopenta[a]phenanthren

diethyl ether

acetic acid

(10R)-3c-Hydroxy-10r.13c-dimethyl-17c-((1R:4R)-1.4.5-trimethyl-hexen-(2t)-yl)-(9cH.14tH)-Δ^5.7-dodecahydro-1H-cyclopenta[a]phenanthren

Downstream raw materials:

C₃₇H₅₆O₄

C₃₈H₅₈O₄

O-(3.5-dinitro-benzoyl)-campestanol

O-Benzoyl-haliclonastanol

Refernces

• 1、 Sepe, Valentina,Di Leva, Francesco Saverio,D'Amore, Claudio,Festa, Carmen,De Marino, Simona,Renga, Barbara,D'Auria, Maria Valeria,Novellino, Ettore,Limongelli, Vittorio,D'Souza, Lisette,Majik, Mahesh,Zampella, Angela,Fiorucci, Stefano. "Marine and semi-synthetic hydroxysteroids as new scaffolds for pregnane X receptor modulation". . p. 3091 - 3115. Retrieved 2014/07/08.
• 2、 Dayal,Ertel,Rapole,Asgaonkar,Salen. "Rapid hydrogenation of unsaturated sterols and bile alcohols using microwaves". . p. 451 - 454. Retrieved 2007/10/03.