Azane;methylcarbamodithioic acid

Base Information

• Chemical Name: Azane;methylcarbamodithioic acid
• CAS No.: 39680-90-5
• Molecular Formula: C2H8N2S2
• Molecular Weight: 124.231
• Wikidata: Q27282839
• Mol file: 39680-90-5.mol

Synonyms:SCHEMBL8333452;LVYAMPSKHSIFNV-UHFFFAOYSA-N;Q27282839

Chemical Property of Azane;methylcarbamodithioic acid

Chemical Property:

• Vapor Pressure: 15.3mmHg at 25°C
• Boiling Point: 120.3°C at 760 mmHg
• Flash Point: 26.6°C
• PSA: 93.20000
• LogP: 1.15570
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 124.01289061
• Heavy Atom Count: 6
• Complexity: 42.9

Purity/Quality:

METAM-AMMONIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CNC(=S)S.N

Technology Process of Azane;methylcarbamodithioic acid

There total 1 articles about Azane;methylcarbamodithioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + methylamine (74-89-5) → N-methylcarbamodithioic acid ammonium salt (39680-90-5)

Guidance literature:

With ammonium hydroxide; In water; at 25 - 30 ℃; for 3h; Sealed tube;

Reference yield: 41.0%

N-methyl-N-chloromethylcarbamoyl chloride (50778-91-1) + N-methylcarbamodithioic acid ammonium salt (39680-90-5) → dazomet (533-74-4) + 3,5-Dimethyl-2-thioxo-[1,3,5]thiadiazinan-4-one (78460-59-0)

Guidance literature:

With triethylamine; In acetone; 1.)ice-water cooling, 1h 2.)r.t., 2 h;

Reference yield:

methyl-dithiocarbamic acid; ammonium salt (39680-90-5) + chloroacetyl chloride (79-04-9) → 3-Methyl-2-thioxo-thiazolidin-4-on (4807-55-0)

Guidance literature:

With triethylamine; In water; acetone; for 0.5h;

upstream raw materials:

carbon disulfide

methylamine

Downstream raw materials:

3,3'-dimethyl-2,2'-dithioxo[5,5']bithiazolidinylidene-4,4'-dione

dazomet

3,5-Dimethyl-2-thioxo-[1,3,5]thiadiazinan-4-one

3-Methyl-2-thioxo-thiazolidin-4-on

Refernces