Tributylmethylstannane

Base Information

• Chemical Name: Tributylmethylstannane
• CAS No.: 1528-01-4
• Molecular Formula: C13H30 Sn
• Molecular Weight: 305.091
• European Community (EC) Number: 216-202-9
• UNII: GK82QCR86H
• DSSTox Substance ID: DTXSID80165121
• Wikidata: Q83034262
• Mol file: 1528-01-4.mol

Synonyms:Tributylmethylstannane;1528-01-4;TRI-N-BUTYLMETHYLTIN;tributyl(methyl)stannane;Methyltributyltin;Stannane, tributylmethyl-;Methyltributylstannane;Stannane,tributylmethyl-;Tributylmethyltin;EINECS 216-202-9;Tributylmonomethyltin;GK82QCR86H;C13H30Sn;C13-H30-Sn;DTXSID80165121;MFCD01862487;AKOS025293685;EN300-8670979

Chemical Property of Tributylmethylstannane

Chemical Property:

• Vapor Pressure: 0.00612mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.4735
• Boiling Point: 122-124°C 11mm
• Flash Point: 127°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 5.46530
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 306.136954
• Heavy Atom Count: 14
• Complexity: 98.6

Purity/Quality:

98%min ^*data from raw suppliers

tri-n-Butylmethyltin ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 23-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Tin Compounds, Organic
• Canonical SMILES: CCCC[Sn](C)(CCCC)CCCC

Technology Process of Tributylmethylstannane

There total 66 articles about Tributylmethylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tributyltin chloride (1461-22-9) + methyl iodide (74-88-4) → methyltributyltin (1528-01-4)

Guidance literature:

With ammonium fluoride; In methanol; Electrochem. Process;

Reference yield: 98.0%

bis(tri-n-butyltin) (813-19-4) → tributyltin iodide (7342-47-4) + methyltributyltin (1528-01-4)

Guidance literature:

With methyl iodide; dichloro bis(acetonitrile) palladium(II); In N,N,N,N,N,N-hexamethylphosphoric triamide; 20°C, molar ratio distannane/halide 1.3:1, 5 min;

DOI:10.1007/BF01141722

Reference yield: 94.0%

methylytterbium (88068-44-4) + bis(tri-n-butyltin)oxide (56-35-9) → methyltributyltin (1528-01-4)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; byproducts: [O(YbI)2]; soln. of Yb-compd. addn. (dropwise, under Ar, Schlenk flask) with Sn-compd., stirring (2-3 h), aq. HCl addn., extraction (ether), extracts drying (MgSO4);

upstream raw materials:

bis(tri-n-butyltin)

methyl iodide

Dibutyl maleate

tri-n-butyl(1,1,2,2,3,3,4,4,4-nonafluorobutyl)stannane

Downstream raw materials:

tributylethylstannane

dibutyltin chloride

C₁₇H₁₉NO₂

methyltrioxorhenium(VII)

Refernces

• 1、 Pace, Vittorio,Castoldi, Laura,Mazzeo, Eugenia,Rui, Marta,Langer, Thierry,Holzer, Wolfgang. "Efficient Access to All-Carbon Quaternary and Tertiary α-Functionalized Homoallyl-type Aldehydes from Ketones". supporting information. p. 12677 - 12682. Retrieved 2017/09/08.
• 2、 -. "METHOD FOR PRODUCING 14 GROUP METAL LITHIUM COMPOUND". Paragraph 0061-0062. . Retrieved 2016/10/31.