Technology Process of Bicyclo[2.2.1]hept-5-ene-2-ethanol, 4-methylbenzenesulfonate, exo-
There total 10 articles about Bicyclo[2.2.1]hept-5-ene-2-ethanol, 4-methylbenzenesulfonate, exo- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) NaBH4, BF3*O(C2H5)2, 2.)aq. NaOH, 30 percent aq. H2O2 / 1.) THF, RT, 3 h, 2.) THF/H2O, 40 deg C, 3 h
2: 42.1 percent / iodine, potassium iodide, NaHCO3 / dioxane; H2O / 1 h / Ambient temperature
3: 75.7 percent / acetic acid, zinc dust / 5 h / Ambient temperature
4: 55 percent / pyridine / 0.08 h / Heating
With
pyridine; sodium hydroxide; sodium tetrahydroborate; boron trifluoride diethyl etherate; dihydrogen peroxide; iodine; sodium hydrogencarbonate; acetic acid; potassium iodide; zinc;
In
1,4-dioxane; water;
DOI:10.1246/bcsj.60.1954
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 75.1 percent / 2 percent aq. HCl / methanol / 3 h / Heating
2: 42.1 percent / iodine, potassium iodide, NaHCO3 / dioxane; H2O / 1 h / Ambient temperature
3: 75.7 percent / acetic acid, zinc dust / 5 h / Ambient temperature
4: 55 percent / pyridine / 0.08 h / Heating
With
pyridine; hydrogenchloride; iodine; sodium hydrogencarbonate; acetic acid; potassium iodide; zinc;
In
1,4-dioxane; methanol; water;
DOI:10.1246/bcsj.60.1954