Imidogen,fluoro-

Base Information

• Chemical Name: Imidogen,fluoro-
• CAS No.: 13967-06-1
• Molecular Formula: FH₂N
• Molecular Weight: 35.021
• Mol file: 13967-06-1.mol

Synonyms:

Chemical Property of Imidogen,fluoro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Imidogen,fluoro-

There total 47 articles about Imidogen,fluoro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + ammonia (7664-41-7) → difluoroamine (10405-27-3) + nitrogen trifluoride (7783-54-2) + nitrosyl fluoride (7789-25-5) + nitrylfluoride (10022-50-1) + N-monofluoroamine (13967-06-1,15861-05-9)

Guidance literature:

In melt; byproducts: N2O, N2, F2; Electrolysis; electrolysis of a molten anhyd. NH3-HF-mixt. (24.5-16% NH3) at 65-40°C;;

Reference yield:

ammonium bifluoride → nitrogen trifluoride (7783-54-2) + N-monofluoroamine (13967-06-1,15861-05-9)

Guidance literature:

In melt; Electrolysis; concn. of NH3 in the melt: 27-22%;;

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + ammonia (7664-41-7) → difluoroamine (10405-27-3) + nitrogen trifluoride (7783-54-2) + N-monofluoroamine (13967-06-1,15861-05-9)

Guidance literature:

In melt; byproducts: N2O; Electrolysis; electrolysis of a molten anhyd. NH3-HF-mixt. (27-24.5% NH3) at 112-65°C;;

upstream raw materials:

fluorine

nitrogen trifluoride

hydrogen

hydrogen fluoride

Downstream raw materials:

hydrogen fluoride

chloroamine

difluoroamine

nitrogen trifluoride

Refernces

• 1、 Davies, P. B.,Temps, F.. "Far infrared laser magnetic resonance spectrum of NF (a 1Δ)". . p. 6556 - 6559. Retrieved 1981.
• 2、 Davis, Steven J.,Piper, Lawrence G.. "Production of N2(B3IIg,v'=1-12) in the Reaction between NF(a1Δ) and N(2D)". . p. 4515 - 4520. Retrieved 1990.
• 3、 David, S. J.,Coombe, R. D.. "Rates of Reactions of the Azide Radical". . p. 3260 - 3263. Retrieved 1986.
• 4、 Davies, P. B.,Hamilton, P. A.,Okumura, M.. "Infrared diode laser spectroscopy of the fundamental band of NF(a 1Δ)". . p. 4294 - 4297. Retrieved 1981.
• 5、 Di Stefano,Lenzi,Piciacchia,Ricci. "Line strengths of diatomics: The b 1Σ+v′=0→X 3Σ-v″=0 transition of the NF radical". . p. 2752 - 2759. Retrieved 1997.
• 6、 Bradburn, Gregory R.,Lilenfeld, Harvey V.. "A Coefficients of the a1Δ States of NF and NH". . p. 555 - 558. Retrieved 1991.
• 7、 Benard, D. J.,Winker, B. K.,Seder, T. A.,Cohn, R. H.. "Production of NF(a1Δ) by Dissociation of Fluorine Azide". . p. 4790 - 4796. Retrieved 1989.
• 8、 Misochko,Gol'dshleger,Akimov. "Reactions of photogenerated fluorine atoms with molecules trapped in solid argon 3. * Formation of stabilized .NH2 radicals and .NH2-HF radical-molecule complexes in the reactions of fluorine atoms with NH3". . p. 829 - 835. Retrieved 2000.
• 9、 Liu, X.,MacDonald, M. A.,Coombe, R. D.. "Rates of Reactions of N3 with F, Cl, Br, and H Atoms". . p. 4907 - 4912. Retrieved 1992.
• 10、 Kung, R. T. V.,Roberts, R.. "". . p. 1433 - 1435. Retrieved 1974.