1-Amino-3-nitroguanidine

Base Information

• Chemical Name: 1-Amino-3-nitroguanidine
• CAS No.: 18264-75-0
• Molecular Formula: CH5 N5 O2
• Molecular Weight: 119.083
• Hs Code.: 2928000090
• European Community (EC) Number: 242-139-1
• Mol file: 18264-75-0.mol

Synonyms:N-Nitrocarbazamidine;1-Amino-3-nitroguanidine;3-Amino-1-nitroguanidine;1-Nitro-3-aminoguanidine;CH5N5O2;18264-75-0;Guanidine, 1-amino-3-nitro-;C-H5-N5-O2;Hydrazinecarboximidamide, N-nitro-;3-amino-1-nitro-guanidine

Chemical Property of 1-Amino-3-nitroguanidine

Chemical Property:

• Melting Point: 187.8°C
• Refractive Index: 1.6000 (estimate)
• Boiling Point: 332.3°Cat760mmHg
• Flash Point: 154.8°C
• PSA: 119.75000
• Density: 2.1g/cm³
• LogP: 0.27080
• Water Solubility.: 2.684g/L(20.96 oC)
• XLogP3: -0.9
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 119.04432442
• Heavy Atom Count: 8
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=NN)(N)N[N+](=O)[O-]
• Isomeric SMILES: C(=N/N)(\N)/N[N+](=O)[O-]

Technology Process of 1-Amino-3-nitroguanidine

There total 15 articles about 1-Amino-3-nitroguanidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

S-methyl-N-nitroisothiourea (2986-25-6) → 1-amino-2-nitroguanidine (18264-75-0)

Guidance literature:

With hydrazine hydrate; In ethanol; for 0.333333h; Heating;

DOI:10.1002/ardp.19843170604

Reference yield: 90.0%

1,2-dinitroguanidine (651322-68-8,666736-83-0) → 1-amino-2-nitroguanidine (18264-75-0)

Guidance literature:

With hydrazine hydrate; In water; at 70 - 80 ℃; for 2h;

DOI:10.1023/A:1026003700547

Reference yield: 88.7%

N-methyl-N''-nitro-N-nitrosoguanidine (70-25-7) → 1-amino-2-nitroguanidine (18264-75-0)

Guidance literature:

With hydrazine hydrate; In water; for 0.333333h;

upstream raw materials:

nitro-azidocarboxamidine

nitroguanidine

methyl nitrocarbamimidothioate

N-butyl-N'-nitro-guanidine

Downstream raw materials:

5-nitro-furfural-(nitrocarbamimidoyl-hydrazone)

N-nitro-N'-(4-nitro-benzylidenamino)-guanidine

N-(4-hydroxy-benzylidenamino)-N'-nitro-guanidine

N-(4-methoxy-benzylidenamino)-N'-nitro-guanidine

Refernces

• 1、 Jin, Xinghui,Hu, Bingcheng,Liu, Zuliang,Lv, Chunxu. "Structure and properties of 1-amino-2-nitroguanidinium nitrate". . p. 23898 - 23903. Retrieved 2014.
• 2、 Fischer, Niko,Joas, Manuel,Klapoetke, Thomas M.,Stierstorfer, Joerg. "Transition metal complexes of 3-Amino-1-nitroguanidine as laser ignitible primary explosives: Structures and properties". . p. 13791 - 13802. Retrieved 2013.
• 3、 -. "A containing 1, 2, 3 - thiadiazole [...] amino guanidine compound synthesis and use". Sheet 0034-0036. . Retrieved 2017/12/28.