NICKELSULFIDE

Base Information

• Chemical Name: NICKELSULFIDE
• CAS No.: 12035-50-6
• Molecular Formula: NiS₂
• Molecular Weight: 122.822
• Mol file: 12035-50-6.mol

Synonyms:Vaesite(7CI,8CI)

Chemical Property of NICKELSULFIDE

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): R45-20/21/22-36/37/38:
• Hazard Codes: T,Xi:
• Statements: R45-20/21/22-36/37/38:
• Safety Statements: S53-26-36/37/39-45:

MSDS Files:

Useful:

Technology Process of NICKELSULFIDE

There total 92 articles about NICKELSULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

nickel(II) chloride hexahydrate + thioacetamide (62-55-5) → nickel(II) sulfide + trinickel tetrasulfide + nickel disulfide (12035-50-6) + nickel(II) hydroxide

Guidance literature:

With ammonium hydroxide; ammonium chloride; In water; NiCl2*6H2O dissolved in distilled water with NH4OH and NH4Cl buffer soln. adjusted the pH to 9.9 at 60°C;

DOI:10.1246/cl.2001.1028

Reference yield: 80.0%

nickel (7440-02-0) → nickel(II) sulfide + trinickel tetrasulfide + nickel disulfide (12035-50-6)

Guidance literature:

With sulfur; In neat (no solvent); stoichiometric amounts of educts, tempering for 8 months at 300°C;;

Reference yield:

nickel (7440-02-0) + sulfur (7704-34-9) → nickel disulfide (12035-50-6)

Guidance literature:

In neat (no solvent); heating stoich. amounts of elements (evac. quartz ampoule, 400°C, ca. 2 weeks), crushing, reheating (700°C, 2 weeks); X-ray powder diffraction;

DOI:10.1016/0022-4596(80)90543-5

upstream raw materials:

sulfur

hydrogen sulfide

nickel(II) oxide

nickel

Refernces

• 1、 Jourshabani, Milad,Shariatinia, Zahra,Achari, Gopal,Langford, Cooper H.,Badiei, Alireza. "Facile synthesis of NiS2 nanoparticles ingrained in a sulfur-doped carbon nitride framework with enhanced visible light photocatalytic activity: Two functional roles of thiourea". . p. 13448 - 13466. Retrieved 2018.
• 2、 Yin, Zhuoxun,Zhang, Shu,Li, Jinlong,Ma, Shangkun,Chen, Wei,Ma, Xinzhi,Zhou, Yang,Zhang, Zhuanfang,Wang, Xin. "In situfabrication of a Ni-Fe-S hollow hierarchical sphere: an efficient (pre)catalyst for OER and HER". . p. 12996 - 13003. Retrieved 2021.
• 3、 Yao,Honig,Hogan,Kannewurf,Spalek. "Electrical properties of NiS2-xSex single crystals: From Mott insulator to paramagnetic metal". . p. 17469 - 17475. Retrieved 1996.
• 4、 Takeuchi, Tomonari,Sakaebe, Hikari,Kageyama, Hiroyuki,Handa, Katsumi,Sakai, Tetsuo,Tatsumi, Kuniaki. "Modification of nickel sulfide by surface coating with TiO2 and ZrO2 for improvement of cycle capability". . p. A958-A966. Retrieved 2009.
• 5、 Wei, Chengzhen,Cheng, Cheng,Cheng, Yanyan,Wang, Yan,Xu, Yazhou,Du, Weimin,Pang, Huan. "Comparison of NiS2 and α-NiS hollow spheres for supercapacitors, non-enzymatic glucose sensors and water treatment". . p. 17278 - 17285. Retrieved 2015.
• 6、 Yao Li,Shi, Wenjuan,Qu, Yuning,Dai, Tangming,Li, Juan,Zhao, Yongnan,Yu, Jianguo. "NiS2 Nanoparticles with Tunable Surface Area As Catalyst for Ethanol Oxidation". . p. 1577 - 1583. Retrieved 2019.
• 7、 Shimizu, Youichi,Yano, Tomoyasu. "A solution route to synthesize nickel thiospinels". . p. 1028 - 1029. Retrieved 2001.
• 8、 Liang, Jie,Wang, Yuanyuan,Liu, Qian,Luo, Yonglan,Li, Tingshuai,Zhao, Haitao,Lu, Siyu,Zhang, Fang,Asiri, Abdullah M.,Liu, Fenggang,Ma, Dongwei,Sun, Xuping. "Electrocatalytic hydrogen peroxide production in acidic media enabled by NiS2nanosheets". . p. 6117 - 6122. Retrieved 2021.
• 9、 Lu, Min,Sun, Ming-Yuan,Guan, Xiao-Hui,Chen, Xue-Mei,Wang, Guang-Sheng. "Controllable synthesis of hollow spherical nickel chalcogenide (NiS2and NiSe2) decorated with graphene for efficient supercapacitor electrodes". . p. 11786 - 11792. Retrieved 2021.
• 10、 Arul Prakasam, Balasubramaniam,Lahtinen, Manu,Peuronen, Anssi,Muruganandham, Manickavachagam,Kolehmainen, Erkki,Haapaniemi, Esa,Sillanp??, Mika. "Synthesis, NMR spectral and single crystal X-ray structural studies on Ni(II) dithiocarbamates. Fabrication of nickel sulfide nanospheres by the solvothermal method". . p. 588 - 596. Retrieved 2014.