Phenylsilanetriol

Base Information

• Chemical Name: Phenylsilanetriol
• CAS No.: 3047-74-3
• Molecular Formula: C6H8 O3 Si
• Molecular Weight: 156.213
• Hs Code.: 2931900090
• European Community (EC) Number: 221-257-7
• UNII: DNR46JQ8BT
• DSSTox Substance ID: DTXSID10184547
• Nikkaji Number: J24.930K
• Wikidata: Q83055457
• Mol file: 3047-74-3.mol

Synonyms:Phenylsilanetriol;trihydroxy(phenyl)silane;3047-74-3;Silanetriol, phenyl-;DNR46JQ8BT;EINECS 221-257-7;Silanetriol, 1-phenyl-;UNII-DNR46JQ8BT;C6H8O3Si;1-PHENYLSILANETRIOL;SCHEMBL273507;C6-H8-O3-Si;DTXSID10184547

Chemical Property of Phenylsilanetriol

Chemical Property:

• Vapor Pressure: 0.00024mmHg at 25°C
• Boiling Point: 311.5°Cat760mmHg
• Flash Point: 142.2°C
• PSA: 60.69000
• Density: 1.31g/cm³
• LogP: -1.19060
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 156.02427065
• Heavy Atom Count: 10
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Si](O)(O)O

Technology Process of Phenylsilanetriol

There total 14 articles about Phenylsilanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tri(benzyloxy)phenylsilane → phenylsilanetriol (3047-74-3)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In ethyl acetate; at 20 ℃; for 12h;

Reference yield: 97.0%

phenyl trimethylsiloxane (2996-92-1,46143-12-8) → phenylsilanetriol (3047-74-3)

Guidance literature:

With water; In acetonitrile; at 25 ℃; for 0.0833333h;

Reference yield: 97.0%

phenylsilane (694-53-1) → phenylsilanetriol (3047-74-3)

Guidance literature:

With water; In tetrahydrofuran; at 20 ℃; for 1.5h;

DOI:10.1002/anie.201101993

upstream raw materials:

phenyl trimethylsiloxane

Phenyltrichlorosilane

phenyl-tris(1,4-dioxapentyl) silane

bis(2-methoxyethoxy)phenylsilanol

Downstream raw materials:

2-methylbiphenyl

1,3-diphenyl-1,1,3,3-tetrahydroxydisiloxane

1,3,5-triphenyl-1,1,3,5,5-pentahydroxytrisiloxane

C₁₈H₁₈O₆Si₃

Refernces

• 1、 Tyler. "-". . p. 770. Retrieved 1955.
• 2、 Chen, Hong,Wang, Yao,Lin, Jianhui,Shuai, Minmin,Zhu, Haidi,Zhang, Wengong,Ling, Qidan. "Transparent red -emitting silicone resin for color conversion and encapsulation of NUV light-emitting diodes". . p. 2718 - 2726. Retrieved 2019.
• 3、 McNeil, K. J.,DiCaprio, J. A.,Walsh, D. A.,Pratt, R. F.. "Kinetics and Mechanism of Hydrolysis of a Silicate Triester, Tris(2-methoxyethoxy)phenylsilane". . p. 1859 - 1865. Retrieved 1980.
• 4、 -. "METHOD FOR PRODUCING SILANOLS AND NOVEL SILANOLS". Paragraph 0053-0054; 0059; 0087-0088. . Retrieved 2021/08/13.
• 5、 Bai, Lu,Fan, Chenghao,Hu, Yanfang,Li, Yonglong,Liu, Jun,Shi, Faxing,Xie, Wei,Yang, Ling,Zhang, Kaifu,Zhao, Yaran. "Synthesis of a Gold–Metal Oxide Core–Satellite Nanostructure for In Situ SERS Study of CuO-Catalyzed Photooxidation". . p. 18003 - 18009. Retrieved 2020/08/21.