Technology Process of Oxiranemethanol, 3-[3,4-bis(methoxymethoxy)phenyl]-
There total 4 articles about Oxiranemethanol, 3-[3,4-bis(methoxymethoxy)phenyl]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tert.-butylhydroperoxide; vanadyl acetylacetonate;
In
dichloromethane; water;
for 6h;
Ambient temperature;
DOI:10.1248/cpb.35.3603
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 96 percent / cc. H2SO4 / 8 h / Heating
2: 1.) sodium hydride (NaH) / 1.) tetrahydrofuran (THF), 0 deg C to room temp., 1 h; 2.) THF, 0 deg C to room temp., 8 h
3: 78 percent / lithium aluminum hydride / diethyl ether; tetrahydrofuran / -10 °C
4: 84 percent / tert-butyl hydroperoxide (70percent), vanadyl acetylacetonate / H2O; CH2Cl2 / 6 h / Ambient temperature
With
tert.-butylhydroperoxide; lithium aluminium tetrahydride; vanadyl acetylacetonate; sulfuric acid; sodium hydride;
In
tetrahydrofuran; diethyl ether; dichloromethane; water;
DOI:10.1248/cpb.35.3603
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) sodium hydride (NaH) / 1.) tetrahydrofuran (THF), 0 deg C to room temp., 1 h; 2.) THF, 0 deg C to room temp., 8 h
2: 78 percent / lithium aluminum hydride / diethyl ether; tetrahydrofuran / -10 °C
3: 84 percent / tert-butyl hydroperoxide (70percent), vanadyl acetylacetonate / H2O; CH2Cl2 / 6 h / Ambient temperature
With
tert.-butylhydroperoxide; lithium aluminium tetrahydride; vanadyl acetylacetonate; sodium hydride;
In
tetrahydrofuran; diethyl ether; dichloromethane; water;
DOI:10.1248/cpb.35.3603