Molybdenumhexacarbonyl

Base Information

• Chemical Name: Molybdenumhexacarbonyl
• CAS No.: 13939-06-5
• Molecular Formula: C₆MoO₆
• Molecular Weight: 264.002
• Hs Code.: 29310095
• European Community (EC) Number: 237-713-3
• Mol file: 13939-06-5.mol

Synonyms:hexacarbonylmolybdenum;Mo(CO)6;molybdenum hexacarbonyl

Chemical Property of Molybdenumhexacarbonyl

Chemical Property:

• Appearance/Colour: White to light yellow crystalline powder
• Vapor Pressure: 0.13 hPa (20 °C)
• Melting Point: 150 °C (dec.)(lit.)
• Boiling Point: 156 °C(lit.)
• PSA: 0.00000
• Density: 1.96 g/mL at 25 °C(lit.)
• LogP: -1.24800
• Storage Temp.: Store at
• Solubility.: Slightly soluble in tetrahydrofuran, diglyme and acetonitrile.
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 265.874891
• Heavy Atom Count: 13
• Complexity: 10

Purity/Quality:

98%,99%, ^*data from raw suppliers

Molybdenum carbonyl, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,Xi
• Hazard Codes: T+,Xi
• Statements: 26/27/28
• Safety Statements: 36/37/39-45-36/37-28A-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo]
• Uses: Plating molybdenum, i.e., molybdenum mir-rors; intermediate. It is used as a catalyst in many organicsynthetic reactions. Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.

Technology Process of Molybdenumhexacarbonyl

There total 154 articles about Molybdenumhexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + carbon monoxide (201230-82-2) → bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + molybdenum hexacarbonyl (13939-06-5,199620-15-0)

Guidance literature:

In tetrahydrofuran; reaction in a calorimeter; CO pressure: 500 psi;

Reference yield: 96.0%

(CO)5MoC(OEt)SiPh3 → molybdenum hexacarbonyl (13939-06-5,199620-15-0) + triphenylhydroxysilane (791-31-1)

Guidance literature:

With carbon monoxide; In diethyl ether; High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;

DOI:10.1016/0022-328X(89)85046-6

Reference yield: 90.0%

(CO)5MoC(OEt)SiPh3 + benzylidene phenylamine (538-51-2) → CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5) + CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) + triphenylhydroxysilane (791-31-1)

Guidance literature:

With carbon monoxide; In diethyl ether; High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;

DOI:10.1016/0022-328X(89)85046-6

upstream raw materials:

carbon monoxide

phosgene

molybdenum

[Mo(η(5)-C5H5)(CO)2(N:CBu(t)2)]

Downstream raw materials:

tetracarbonyl-bis(diphenylphosphino)methane-molybdenum⁽⁰⁾

triphenylphosphinemolybdenumpentacarbonyl

(tetraphenylphosphonium)[CpMo(CO)3]

P(C₆H₅)4⁽¹⁺⁾*Mo(CH₃COS)3^(1-)=P(C₆H₅)4[Mo(CH₃COS)3]

Refernces

• 1、 Bochmann, Manfred,Green, Michael,Kirsch, Howard P.,Stone, F. Gordon A.. "". . . Retrieved 1977.
• 2、 Curtis, M. David,Shiu, Kom-Bei,Butler, W. M.,Huffman, John C.. "Syntheses, Structures, and Molecular Orbital Analysis of Hydridotris(pyrazolyl)borate (Tp) Molybdenum Carbonyls: Paramagnetic TpMo(CO)3 and Triply Bonded Tp2Mo2(CO)4 (Mo Mo)". . p. 3335 - 3343. Retrieved 1986.
• 3、 Lindner, Ekkehard,Pabel, Michael,Fawzi, Riad,Mayer, Hermann A.,Wurst, Klaus. "Synthese und Reaktivitaet kohlenwasserstoffueberbrueckter Komplexe von Mangan, Rhenium, Molybdaen und Wolfram". . p. 109 - 121. Retrieved 1992.
• 4、 McGhee, William D.,Sella, Andrea,O'Hare, Dermot,Cloke, F. Geoffrey N.,Mehnert, Christian,Green, Malcolm L. H.. "Synthesis and structure of the first η6-pyrazine complex 6-Me4pyrazine)2> and related studies". . p. 125 - 130. Retrieved 1993.
• 5、 Lorber, Christian,Vendier, Laure. "Imido-titanium/molybdenum heterobimetallic systems. Switching from η6-arene to fischer-type aminocarbene complexes by tuning reactivity conditions". . p. 1127 - 1136. Retrieved 2010.
• 6、 Braunschweig, Holger,Forster, Melanie,Kupfer, Thomas,Seeler, Fabian. "Borylene transfer under thermal conditions for the synthesis of rhodium and iridium borylene complexes". . p. 5981 - 5983. Retrieved 2008.
• 7、 Chang, Biau-Hung. "". . p. L189 - L192. Retrieved 1982.
• 8、 Braunschweig, Holger,Ye, Qing,Radacki, Krzysztof,Brenner, Peter,Frenking, Gernot,De, Susmita. "Borylene-based functionalization of iron-alkynyl-σ-complexes and stepwise reversible metal-boryl-to-borirene transformation: Synthesis, characterization, and density functional theory studies". . p. 62 - 71. Retrieved 2011/02/27.
• 9、 Alvarez, M. Angeles,Garcia, M. Esther,Garcia-Vivo, Daniel,Martinez, M. Eugenia,Ruiz, Miguel A.. "Binuclear carbyne and ketenyl derivatives of the alkyl-bridged complexes [Mo2(η5-C5H5) 2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph)". . p. 2189 - 2199. Retrieved 2011/05/11.