Technology Process of Stannane, trimethyl(1-phenylethenyl)-
There total 3 articles about Stannane, trimethyl(1-phenylethenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
magnesium;
In
tetrahydrofuran;
under Ar, soln. of Br-compd. added slowly to Mg in THF with refluxing, refluxed, cooled to room temp., soln. of Me3SnCl added, stirred for several h; ether and saturated NH4Cl-soln. added, organic layer dried over MgSO4, fractionated, elem. anal.;
DOI:10.1021/om00125a015
- Guidance literature:
-
With
methyl magnesium iodide;
copper(l) cyanide;
In
tetrahydrofuran; diethyl ether;
byproducts: α-methylstyrene; to soln. of MeLi in Et2O added suspn. of anhyd. SnCl2 in THF at 0 °C, after stirring for 20 min added soln. of MeMgI in Et2O at 0 °C, stirred for 15 min CuCN and soln. of alkene in THF added successively, stirred for 5 h at room temp.; poured into aq. satd. soln. of NH4Cl, extd. (Et2O), org. layer washed with brine, dried over Na2SO4, concd., cromd. (SiO2);
DOI:10.1016/0022-328X(85)87365-4
- Guidance literature:
-
In
tetrahydrofuran;
50°C, 2 h;;
