Technology Process of Lithium, [bis(2,4,6-trimethylphenyl)germyl]-
There total 1 articles about Lithium, [bis(2,4,6-trimethylphenyl)germyl]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
byproducts: t-BuH; Addn. of a soln. of t-butyllithium in pentane to a soln. of {C6H2(CH3)3}2GeH2 in THF (-20 °C, 40 min).; {C6H2(CH3)3}2GeH2 is detected by H NMR, 13C NMR and IR. Not isolated in solid state.;
DOI:10.1016/0022-328X(88)80051-2
- Guidance literature:
-
With
hydrogenchloride;
In
tetrahydrofuran;
addn. of Mes2GeHLi (from t-BuLi and Mes2GeH2 in anhyd. THF) to Mes2SiCl2 in THF at -23°C under dry Ar, warming to 20°C, stirring (21 h), addn. of 1 M HCl; triturating with methanol; elem. anal.;
DOI:10.1021/om00042a035
- Guidance literature:
-
With
methyl iodide;
In
tetrahydrofuran;
inert atmosphere; excess MeI, -20°C, then 20°C, 2 h; hydrolysis, extn., concentration (vac.); elem. anal.;
DOI:10.1021/om00115a032
