Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium

Base Information

• Chemical Name: Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium
• CAS No.: 127175-63-7
• Molecular Formula: C28H31O7S
• Molecular Weight: 511.616
• DSSTox Substance ID: DTXSID001145867
• Mol file: 127175-63-7.mol

Synonyms:SCHEMBL9658092;DTXSID001145867;Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium;127175-63-7

Chemical Property of Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium

Chemical Property:

• XLogP3: 7.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 11
• Exact Mass: 511.17904950
• Heavy Atom Count: 36
• Complexity: 654

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)OC(=O)OC1=CC=C(C=C1)[S+](C2=CC=C(C=C2)O)C3=CC=C(C=C3)OC(=O)OC(C)(C)C

Technology Process of Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium

There total 3 articles about Bis[4-[[(1,1-dimethylethoxy)carbonyl]oxy]phenyl](4-hydroxyphenyl)sulfonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(4-tert-butoxycarbonyloxyphenyl)sulfonium trifluoromethylsulphonate → 4,4'-Thiodiphenol (2664-63-3) + tris(4-hydroxyphenyl)sulphonium (88101-75-1) + C22H26O6S (138888-97-8) + (4-tert-Butoxycarbonyloxy-phenyl)-bis-(4-hydroxy-phenyl)-sulfonium (138888-96-7) + Bis-(4-tert-butoxycarbonyloxy-phenyl)-(4-hydroxy-phenyl)-sulfonium (127175-63-7)

Guidance literature:

In water; acetonitrile; Product distribution; Quantum yield; Mechanism; Ambient temperature; Irradiation; other solvent;

DOI:10.1039/P29910001803

Reference yield:

tris(4-tert-butoxycarbonyloxyphenyl)sulfonium trifluoromethylsulphonate → 4,4'-Thiodiphenol (2664-63-3) + tris(4-hydroxyphenyl)sulphonium (88101-75-1) + (4-tert-Butoxycarbonyloxy-phenyl)-bis-(4-hydroxy-phenyl)-sulfonium (138888-96-7) + Bis-(4-tert-butoxycarbonyloxy-phenyl)-(4-hydroxy-phenyl)-sulfonium (127175-63-7)

Guidance literature:

In acetonitrile; Product distribution; Quantum yield; Mechanism; Ambient temperature; Irradiation; without water, other solvents;

DOI:10.1039/P29910001803

Reference yield:

tris(4-tert-butoxycarbonyloxyphenyl)sulfonium hexafluoroarsenate → 4,4'-Thiodiphenol (2664-63-3) + tris(4-hydroxyphenyl)sulphonium (88101-75-1) + (4-tert-Butoxycarbonyloxy-phenyl)-bis-(4-hydroxy-phenyl)-sulfonium (138888-96-7) + Bis-(4-tert-butoxycarbonyloxy-phenyl)-(4-hydroxy-phenyl)-sulfonium (127175-63-7)

Guidance literature:

In acetonitrile; Product distribution; Quantum yield; Mechanism; Ambient temperature; Irradiation; without water, other solvents;

DOI:10.1039/P29910001803

Refernces