Benzoic acid, 4,4'-[iminobis(methylene)]bis-, diethyl ester

Base Information

• Chemical Name: Benzoic acid, 4,4'-[iminobis(methylene)]bis-, diethyl ester
• CAS No.: 131065-88-8
• Molecular Formula: C20H23NO4
• Molecular Weight: 341.407
• Mol file: 131065-88-8.mol

Synonyms:

Chemical Property of Benzoic acid, 4,4'-[iminobis(methylene)]bis-, diethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 4,4'-[iminobis(methylene)]bis-, diethyl ester

There total 6 articles about Benzoic acid, 4,4'-[iminobis(methylene)]bis-, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ N,N-bis(p-ethyloxycarbonylbenzyl)amine (131065-88-8)

Guidance literature:

With borane-ammonia complex; C₁₆H₂₉Cl₂CoN₂P; at 25 ℃; for 13h; Inert atmosphere; Schlenk technique;

Reference yield: 72.0%

ethyl 4-cyanobenzoate (7153-22-2) → N,N-bis(p-ethyloxycarbonylbenzyl)amine (131065-88-8)

Guidance literature:

With hydrogen; rhodium on aluminium; In acetic acid; at 23 ℃; under 760 Torr;

DOI:10.1021/jo00001a088

Reference yield:

C20H21NO4 → N,N-bis(p-ethyloxycarbonylbenzyl)amine (131065-88-8)

Guidance literature:

With sodium tetrahydroborate; In ethanol; at 20 ℃;

DOI:10.1021/jm0309708

upstream raw materials:

ethyl 4-cyanobenzoate

p-ethoxycarbonylbenzaldehyde

p-(Aminometyl)benzoic acid ethyl ester hydrochloride

Refernces

• 1、 -. "Cobalt complex, preparation method thereof, and application thereof in selective catalysis of transfer hydrogenation reaction of cyano group". Paragraph 0165-0167; 0169. . Retrieved 2018/05/07.