Trimethyltin chloroacetate

Base Information

• Chemical Name: Trimethyltin chloroacetate
• CAS No.: 15239-22-2
• Molecular Formula: C₅H₁₁ClO₂Sn
• Molecular Weight: 257.304
• DSSTox Substance ID: DTXSID20586699
• NSC Number: 173045
• Mol file: 15239-22-2.mol

Synonyms:15239-22-2;Trimethyltin chloroacetate;DTXSID20586699;NSC173045;[(Chloroacetyl)oxy](trimethyl)stannane;NSC-173045;Stannane, [(chloroacetyl)oxy]trimethyl-

Chemical Property of Trimethyltin chloroacetate

Chemical Property:

• Vapor Pressure: 0.259mmHg at 25°C
• Boiling Point: 189°Cat760mmHg
• Flash Point: 71.5°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 257.946960
• Heavy Atom Count: 9
• Complexity: 108

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)OC(=O)CCl

Technology Process of Trimethyltin chloroacetate

There total 4 articles about Trimethyltin chloroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetramethylstannane (594-27-4) + mercury(II) chloroacetate (26719-07-3) → Methylquecksilber(II)monochloracetat (21777-78-6) + Trimethylzinnchloracetat (15239-22-2)

Guidance literature:

In dichloromethane; at 25°C; Kinetics;

DOI:10.1021/ja00544a022

Reference yield:

2-chloro-O-deuterio-acetic acid (1837-59-8) + trimethyl(trimethylstannanylethynyl)silane (16035-50-0) → Trimethylzinnchloracetat (15239-22-2)

Guidance literature:

In chloroform-d1; byproducts: (CH3)3SiCCH; react. in a NMR-tube at 23°C, addn. of the carboxylic acid soln. to the compd.; detected by NMR; Kinetics;

Reference yield:

trimethyl(trimethylstannanylethynyl)silane (16035-50-0) + chloroacetic acid (79-11-8) → Trimethylzinnchloracetat (15239-22-2)

Guidance literature:

In chloroform-d1; byproducts: (CH3)3SiCCH; react. in a NMR-tube at 23°C, addn. of the carboxylic acid soln. to the compd.; detected by NMR; Kinetics;

upstream raw materials:

tetramethylstannane

mercury(II) chloroacetate

2-chloro-O-deuterio-acetic acid

trimethyl(trimethylstannanylethynyl)silane

Refernces

• 1、 Fukuzumi, S.,Kochi, J. K.. "Electron-Transfer Activation in Electrophilic Mechanisms. Cleavage of Alkylmetals by Mercury(II) Complexes". . p. 7290 - 7297. Retrieved 2007/10/02.