2,3,4-Trimethylaniline

Base Information

• Chemical Name: 2,3,4-Trimethylaniline
• CAS No.: 1467-35-2
• Molecular Formula: C9H13 N
• Molecular Weight: 135.209
• Hs Code.: 2921430090
• European Community (EC) Number: 215-989-6
• UNII: XY34EQP4HG
• DSSTox Substance ID: DTXSID10163453
• Nikkaji Number: J206.672F
• Wikidata: Q83032341
• Mol file: 1467-35-2.mol

Synonyms:2,3,4-Trimethylaniline;1467-35-2;Benzenamine, 2,3,4-trimethyl-;XY34EQP4HG;2,3,4-trimethylbenzenamine;EINECS 215-989-6;Benzenamine, trimethyl-;trimethylphenylamine;UNII-XY34EQP4HG;SCHEMBL33509;DTXSID10163453;AMY28420;BAA46735;AKOS006344003;AS-59880;CS-0158122;A848093

Chemical Property of 2,3,4-Trimethylaniline

Chemical Property:

• Boiling Point: 244.6°Cat760mmHg
• Flash Point: 107.8°C
• PSA: 26.02000
• Density: 0.962g/cm³
• LogP: 2.77520
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 135.104799419
• Heavy Atom Count: 10
• Complexity: 111

Purity/Quality:

99%, ^*data from raw suppliers

2,3,4-TRIMETHYLANILINE ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C(=C(C=C1)N)C)C

Technology Process of 2,3,4-Trimethylaniline

There total 9 articles about 2,3,4-Trimethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

(2,3,4-trimethyl-phenyl)-hydrazine (74404-35-6) → 2,3,4-trimethylaniline (1467-35-2)

Guidance literature:

nickel; In ethanol; for 4h; Heating;

DOI:10.1021/ja00534a033

Reference yield:

→ 2,3,4-trimethylaniline (1467-35-2)

Guidance literature:

With calcium hydroxide;

DOI:10.1039/jr9440000109

Reference yield:

2,3,4-trimethyl-1-nitrobenzene (1128-19-4) → 2,3,4-trimethylaniline (1467-35-2)

Guidance literature:

With sodium dithionite;

upstream raw materials:

2,3,4-trimethyl-1-nitrobenzene

1-(2,3,4-Trimethyl-phenyl)-ethan-1-on-oxim

azidocarbonyl-4 hemimellitene

tosyldiazoamino-4 hemimellitene

Downstream raw materials:

acetic acid-(2,3,4-trimethyl-anilide)

Trimethyl-(3,4,5-trimethyl-phenyl)-silane

amino-4 bromo-5 hemimellitene

1-iodo-2,3,4-trimethylbenzene

Refernces

• 1、 Gruber, Rene,Kirsch, Gilbert,Cagniant, Denise. "Hydrocarbures arylaliphatiques. Partie VIII. Etude cinetique de la protodesilylation de benzocyclenes tricycliques". . p. 498 - 504. Retrieved 2007/10/02.