tin tetrabutanolate

Base Information

• Chemical Name: tin tetrabutanolate
• CAS No.: 14254-05-8
• Molecular Formula: C₈H₁₈O₂Sn
• Molecular Weight: 264.94
• Mol file: 14254-05-8.mol

Synonyms:Butylalcohol, tin(4+) salt (8CI); Butyl stannate(IV) (6CI,7CI); Tetrabutoxystannane;Tetrabutoxytin; Tetrabutyl stannate; Tin (IV) butylate; Tin tetra-n-butoxide;Tin tetrabutoxide

Chemical Property of tin tetrabutanolate

Chemical Property:

• Melting Point: -89.8oC
• Boiling Point: 117.7°Cat760mmHg
• Flash Point: 35°C
• PSA: 20.23000
• Density: 0.805g/cm³
• LogP: -0.13740

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tin tetrabutanolate

There total 4 articles about tin tetrabutanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.79%

tin(ll) chloride + butan-1-ol (71-36-3) → tin(II) n-butoxide (14254-05-8,26306-46-7,130287-64-8)

Guidance literature:

With diethylamine; In n-heptane; at 15 - 38 ℃; Inert atmosphere;

Reference yield:

tin (7440-31-5) + butan-1-ol (71-36-3) → tin(II) n-butoxide (14254-05-8,26306-46-7,130287-64-8)

Guidance literature:

With lithium chloride or (C₂H₅)3CH₂C₆H₅NCl or n-C₄H₉NBr; In butan-1-ol; Electrolysis; (N2 or Ar); using of Sn as anode and stainless steel plate as cathode; electrolysis for 1-1.5 h with soln. of electrolyte LiCl, Bu4NBr or Et3BzNC in n-butanol; sepn. from electrolyte, washing with absolute alcohol; drying in vac.; elem. anal.;

DOI:10.1134/S0036023607110083

Reference yield:

tin(II) bis(methoxide) (14794-99-1,27961-67-7) + butan-1-ol (71-36-3) → tin(II) n-butoxide (14254-05-8,26306-46-7,130287-64-8)

Guidance literature:

In toluene; an excess of n-butanol was aded to a soln. of Sn(OCH3)2 in toluene; Gsell, R.; Zeldin, M. J. Inorg. Nucl. Chem. 1975,37,1133;

DOI:10.1021/ic0100368

upstream raw materials:

tin

butan-1-ol

tin(II) bis(methoxide)

Downstream raw materials:

C₆H₅P(CH₂CH₂S)2Sn

Refernces

• 1、 Yoon, Sung Cheol,Park, And Seung Young,Lee, Kang Mun,Lee, Min Hyung. "Bulk polymerization of L-lactide with dibenzoylmethane Sn(II) compounds". . p. 340 - 345. Retrieved 2015/03/03.
• 2、 -. "ORGANOTIN COMPOUND, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING POLYLACTIDE USING SAME". Page/Page column 9. . Retrieved 2012/08/14.