CID 16685090

Base Information

• Chemical Name: CID 16685090
• CAS No.: 21260-46-8
• Molecular Formula: C9H18 Bi N3 S6
• Molecular Weight: 569.638
• Mol file: 21260-46-8.mol

Synonyms:

Chemical Property of CID 16685090

Chemical Property:

• Appearance/Colour: Yellow powder
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 230 ºC
• Boiling Point: 129.4 °C at 760 mmHg
• Flash Point: 32 °C
• PSA: 242.52000
• Density: g/cm³
• LogP: 1.48500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 568.96290
• Heavy Atom Count: 19
• Complexity: 295

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C(=S)S[Bi](SC(=S)N(C)C)SC(=S)N(C)C
• Uses: Accelerator for natural rubber and SBR, espe- cially in cable covers and mechanical items.

Technology Process of CID 16685090

There total 1 articles about CID 16685090 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

bismuth (7440-69-9) + Thiram (137-26-8,93196-73-7) → tris(dimethyldithiocarbamato)bismuth(III) (21260-46-8)

Guidance literature:

In toluene; metal and S-compd. were refluxed in 1:1.5 molar ratio in toluene for 3 h; soln. was filtered, concd. to 1/3 of its original vol., cooled to room temp., solid was filtered off, washed with petroleum ether (b.p. 60-80 °C), dried in vac., elem. anal.;

DOI:10.1081/SIM-100104783

Reference yield:

tris(dimethyldithiocarbamato)bismuth(III) (21260-46-8) + Bi[S2CN(CH2C6H5)2]3 → Bi[S2CN(CH3)2]2[S2CN(CH2C6H5)2] (91864-87-8)

Guidance literature:

In benzene; stirred for 45 min at 40 - 50°C; concd. at 0.01 Torr, preparative tlc (xylene), extd. (benzene inert atmosphere), evapd. in vacuo;

upstream raw materials:

bismuth

Thiram

Downstream raw materials:

Bi[S₂CN(CH₃)2]2[S₂CN(CH₂C₆H₅)2]

Refernces