Arsonium, methyltriphenyl-, bromide

Base Information

• Chemical Name: Arsonium, methyltriphenyl-, bromide
• CAS No.: 14002-59-6
• Molecular Formula: Br*C₁₉H₁₈As
• Molecular Weight: 401.178
• Mol file: 14002-59-6.mol

Synonyms:

Chemical Property of Arsonium, methyltriphenyl-, bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Arsonium, methyltriphenyl-, bromide

There total 2 articles about Arsonium, methyltriphenyl-, bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl bromide (74-83-9) + triphenyl-arsane (603-32-7) → triphenylmethylarsonium bromide (14002-59-6)

Guidance literature:

at 20 ℃; bei 14-taegiger Einw_. im Rohr;

Reference yield:

→ triphenylmethylarsonium bromide (14002-59-6)

Guidance literature:

Methyl-triphenylarsoniumbromid, HgBr, LiBr;

DOI:10.1016/S0022-328X(00)93861-0

Reference yield:

vinyllithium (917-57-7) + triphenylmethylarsonium bromide (14002-59-6) + trifluoroborane diethyl ether (109-63-7) → methyltriphenylarsonium tetravinylborate

Guidance literature:

In ethanol; (C2H5)2O*BF3 is refluxed with vinyllithium under N2; after filtering the inorganic solids ether is evapd. under reduced pressure; addn. of bromide in ethanolic soln.; recrystn. from ethanol;

DOI:10.1021/ja01478a010

upstream raw materials:

methyl bromide

triphenyl-arsane

Downstream raw materials:

methylenetriphenylarsorane

Ethyltriphenylarsonium-bromid

As(CH₃)(C₆H₅)3⁽¹⁺⁾*Cu(S₂C₆H₂(C(CH₃)3)2)2^(1-)=As(CH₃)(C₆H₅)3Cu(S₂C₆H₂(C(CH₃)3)2)2