N-Nitrodiethylamine

Base Information

• Chemical Name: N-Nitrodiethylamine
• CAS No.: 7119-92-8
• Molecular Formula: C4H10 N2 O2
• Molecular Weight: 118.136
• Hs Code.: 2928000090
• NSC Number: 36184
• UNII: D7TJ0C6RJO
• DSSTox Substance ID: DTXSID50221389
• Wikidata: Q27276226
• Mol file: 7119-92-8.mol

Synonyms:diethylnitramine;N-nitrodiethylamine

Chemical Property of N-Nitrodiethylamine

Chemical Property:

• Vapor Pressure: 0.34mmHg at 25°C
• Refractive Index: 1.4386 (estimate)
• Boiling Point: 206.5°C at 760 mmHg
• Flash Point: 81°C
• PSA: 49.06000
• Density: 1.03g/cm³
• LogP: 1.04310
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 118.074227566
• Heavy Atom Count: 8
• Complexity: 74.6

Purity/Quality:

99%, ^*data from raw suppliers

N-NITRODIETHYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)[N+](=O)[O-]

Technology Process of N-Nitrodiethylamine

There total 9 articles about N-Nitrodiethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethylammonium, NO3(1-)-salt (27096-30-6) → N-Nitrosodiethylamine (55-18-5) + diethyl-N-nitroamine (7119-92-8)

Guidance literature:

With nitric acid; acetic anhydride; zinc(II) chloride; In carbon dioxide; at 20 ℃; for 24h; under 45004.5 - 60006 Torr; Autoclave;

DOI:10.1007/s11172-009-0282-1

Reference yield:

N,N-diethylcarbamyl chloride (88-10-8) → N-Nitrosodiethylamine (55-18-5) + diethyl-N-nitroamine (7119-92-8)

Guidance literature:

With silver nitrate; acetonitrile;

DOI:10.1021/ja01522a047

Reference yield:

diethylamine (109-89-7) → N-Nitrosodiethylamine (55-18-5) + diethyl-N-nitroamine (7119-92-8)

Guidance literature:

With potassium hydroxide; tetra(n-butyl)ammonium hydroxide; potassium nitrate; In dichloromethane; water; Product distribution; Mechanism; electrolysis, Pt anode; other amines;

upstream raw materials:

N,N-diethylcarbamyl chloride

2-cyano-N,N-diethylacetamide

diethylamine

diethyl ether

Downstream raw materials:

formaldoxime

N-Nitrosodiethylamine

diethyl nitroxide

cis-nitrous acid

Refernces

• 1、 Masuda, Mitsuharu,Mower, Howard F.,Pignatelli, Brigitte,Celan, Irena,Friesen, Marlin D.,Nishino, Hoyoku,Ohshima, Hiroshi. "Formation of N-nitrosamines and N-nitramines by the reaction of secondary amines peroxynitrite and other reactive nitrogen species: Comparison with nitrotyrosine formation". . p. 301 - 308. Retrieved 2007/10/03.
• 2、 Andreev, S. A.,Lebedev, B. A.,Tselinskii, I. V.,Shokhor, I. N.. "N-Nitration of amides. VI. Mechanism of nitrolysis of N,N-dialkylamides of carboxylic acids by nitronium tetrafluoroborate in acetonitrile". . p. 1159 - 1166. Retrieved 2007/10/02.