Triethyloxonium hexafluorophosphate

Base Information

• Chemical Name: Triethyloxonium hexafluorophosphate
• CAS No.: 17950-40-2
• Molecular Formula: C6H15F6OP
• Molecular Weight: 248.149
• Hs Code.: 2942000090
• European Community (EC) Number: 241-876-6
• NSC Number: 176022
• DSSTox Substance ID: DTXSID50885001
• Mol file: 17950-40-2.mol

Synonyms:Triethyloxonium hexafluorophosphate;17950-40-2;Triethyloxonium hexafluorophosphate(1-);Oxonium, triethyl-, hexafluorophosphate(1-);triethyloxidanium;hexafluorophosphate;EINECS 241-876-6;Oxonium, triethyl-, hexafluorophosphate(1-) (1:1);NSC 176022;C6H15O.F6P;DTXSID50885001;Oxonium, hexafluorophosphate(1-);C6-H15-O.F6-P;MFCD00044222;NSC176022;triethyloxonium hexafluorophosphate(V);NSC-176022;FT-0637632;J-011458

Chemical Property of Triethyloxonium hexafluorophosphate

Chemical Property:

• Vapor Pressure: 1.84E-06mmHg at 25°C
• Melting Point: ~145 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 22.82000
• Density: g/cm³
• LogP: 4.98080
• Storage Temp.: −20°C
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 248.07647107
• Heavy Atom Count: 14
• Complexity: 88.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethyloxonium hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,F
• Statements: 35-19-11
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[O+](CC)CC.F[P-](F)(F)(F)(F)F
• Uses: Reactant or reagent involved in:Synthesis of ruthenium allenylidene complexesAsymmetric Diels-Alder reactionsChlorine scavengingSynthesis of molecules for studies of wavelength tunability via cis-trans isomerizationReactions with 2-mthylpyridine N-oxideCatalyst activating agent for asymmetric imine aziridination via diazo ester activation

Technology Process of Triethyloxonium hexafluorophosphate

There total 1 articles about Triethyloxonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethyl ether (60-29-7,927820-24-4) + orthoformic acid triethyl ester (122-51-0) → triethyloxonium hexaflourophosphate (17950-40-2)

Guidance literature:

With phosphorus pentafluoride;

DOI:10.1055/s-1973-22241

Reference yield: 99.0%

triethyloxonium hexaflourophosphate (17950-40-2) + 1-benzyloxyimidazole 3-oxide (1027036-69-6) → 1-benzyloxy-3-ethyloxyimidazolium hexafluoridophosphate

Guidance literature:

In dichloromethane;

DOI:10.1515/znb-2017-0089

Reference yield: 99.0%

(S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropionamide (88463-18-7,35150-06-2) + triethyloxonium hexaflourophosphate (17950-40-2) → 2(S)--3-phenylpropanimino ethyl ether (132402-59-6)

Guidance literature:

In dichloromethane; Ambient temperature;

DOI:10.1016/S0040-4020(01)81482-4

upstream raw materials:

diethyl ether

orthoformic acid triethyl ester

Downstream raw materials:

2(S)--3-phenylpropanimino ethyl ether

2-allyloxycarbonylamino-3-phenyl-(S)-propioimino ethyl ether

1,1-Dimethyl-2-ethyl-5-oxo-3-phenoxy-1,2,4-triazolium hexafluorophosphate

5,7-dimethyl-3-(ethylthio)-2-phenyl-1-oxopyrazolo<1,2-a>pyrazolium hexafluorophosphate