1-tert-butyl-1,2,2-trimethylhydrazine

Base Information

• Chemical Name: 1-tert-butyl-1,2,2-trimethylhydrazine
• CAS No.: 60678-73-1
• Molecular Formula: C₇H₁₈N₂
• Molecular Weight: 130.233
• Mol file: 60678-73-1.mol

Synonyms:Hydrazine,(1,1-dimethylethyl)trimethyl- (9CI);Tert-butyl trimethylhydrazine;

Chemical Property of 1-tert-butyl-1,2,2-trimethylhydrazine

Chemical Property:

• Vapor Pressure: 7.48mmHg at 25°C
• Refractive Index: 1.44
• Boiling Point: 136.1 °C at 760 mmHg
• Flash Point: 26.7 °C
• Density: 0.82 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-tert-butyl-1,2,2-trimethylhydrazine

There total 2 articles about 1-tert-butyl-1,2,2-trimethylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + tert-butyl-hydrazine dihydrochloride → Trimethyl-t-butyl-hydrazin (60678-73-1)

Guidance literature:

Multistep reaction; (i) aq. NaOH, (ii) NaBH₃CN, MeCN;

DOI:10.1021/ja00433a036

Reference yield:

dimethylaminopyrrolidine (53779-90-1) + N-tert-Butyl-N',N',N''-trimethyl-hydrazine (93473-68-8) → Trimethyl-t-butyl-hydrazin (60678-73-1) + Dimethyl-pyrrolidin-1-yl-amine (106403-60-5)

Guidance literature:

In chloroform; benzene; at 276.9 ℃; Rate constant; Thermodynamic data; ΔG(excit); insitu ionization;

DOI:10.1021/ja00239a015

Reference yield:

Trimethyl-t-butyl-hydrazin (60678-73-1) + 1,2-Dimethyl-1,2,3,6-tetrahydro-pyridazine (116257-44-4) → N-tert-Butyl-N',N',N''-trimethyl-hydrazine (93473-68-8) + 1,2-Dimethyl-1,2,3,6-tetrahydropyridazin (26163-36-0,53379-14-9)

Guidance literature:

In chloroform; benzene; at 276.9 ℃; Rate constant; Thermodynamic data; ΔG(excit); insitu ionization;

DOI:10.1021/ja00239a015

upstream raw materials:

formaldehyd

dimethylaminopyrrolidine

N-tert-Butyl-N',N',N''-trimethyl-hydrazine

Downstream raw materials:

N-tert-Butyl-N',N',N''-trimethyl-hydrazine

1,2-Dimethyl-1,2,3,6-tetrahydropyridazin

Refernces