Disulfide, bis(dipropylthiocarbamoyl)

Base Information

• Chemical Name: Disulfide, bis(dipropylthiocarbamoyl)
• CAS No.: 2556-42-5
• Molecular Formula: C14H28 N2 S4
• Molecular Weight: 352.654
• European Community (EC) Number: 219-871-5
• DSSTox Substance ID: DTXSID80180253
• Nikkaji Number: J42.231B
• Wikidata: Q83050793
• ChEMBL ID: CHEMBL4757113
• Mol file: 2556-42-5.mol

Synonyms:Tetrapropylthiuram disulphide;Thiuram, tetrapropyl-, disulfide;Tetrapropylthioperoxydicarbamic acid;DISULFIDE, BIS(DIPROPYLTHIOCARBAMOYL);tetra-n-Propylthiuramdisulfide;Tetra-n-propylthiuram disulfide;EINECS 219-871-5;2556-42-5;Tetrapropylthiuram disulfide;BRN 1714218;AI3-14919;CHEMBL4757113;4-04-00-00491 (Beilstein Handbook Reference);Thioperoxydicarbonic diamide (((H2N)C(S))2S2), tetrapropyl-;Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetrapropyl-;Tetrapropylthiuramdisulfid;SCHEMBL442690;tetra-n-propyl thiuram disulfide;DTXSID80180253;C14H28N2S4;Bis(dipropylthiocarbamoyl) disulfide;BDBM50555841;Tetrapropylthioperoxydicarbonic diamide;LS-63050;Formamide, 1,1'-dithiobis*N,N-dipropylthio-;Formamide, 1,1'-dithiobis[N,N-dipropylthio-;Thioperoxydicarbonic diamide (((H2-N)C(S))2-S2), tetrapropyl-

Chemical Property of Disulfide, bis(dipropylthiocarbamoyl)

Chemical Property:

• Vapor Pressure: 1.86E-07mmHg at 25°C
• Boiling Point: 425.8°Cat760mmHg
• Flash Point: 211.3°C
• Density: 1.13g/cm³
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 11
• Exact Mass: 352.11353360
• Heavy Atom Count: 20
• Complexity: 244

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCN(CCC)C(=S)SSC(=S)N(CCC)CCC

Technology Process of Disulfide, bis(dipropylthiocarbamoyl)

There total 5 articles about Disulfide, bis(dipropylthiocarbamoyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.2%

carbon disulfide (75-15-0,12122-00-8) + di-n-propylamine (142-84-7) → tetrapropyl thiuram disulfide (2556-42-5)

Guidance literature:

With oxygen; In isopropyl alcohol; at 50 ℃; for 1.41667h; under 1275.13 Torr; Autoclave;

DOI:10.1080/00397910903537331

Reference yield:

N,N'-dipropyldithiocarbamate sodium (4143-50-4) → tetrapropyl thiuram disulfide (2556-42-5)

Guidance literature:

With lanthanum(III) chloride; In water; Heating;

DOI:10.1107/S010827019801573X

Reference yield:

→ tetrapropyl thiuram disulfide (2556-42-5)

Guidance literature:

With ethanol; iodine;

upstream raw materials:

N,N'-dipropyldithiocarbamate sodium

carbon disulfide

di-n-propylamine

Downstream raw materials:

N,N-dipropylcarbamoyl chloride

copper(II) di-n-propyldithiocarbamate

C₁₃H₂₆N₂S₂

Refernces

• 1、 Xu, Hao-Xing,Zhao, Ze-Run,Patehebieke, Yeersen,Chen, Qian-Qian,Fu, Shun-Guo,Chang, Shuai-Jun,Zhang, Xu-Xu,Zhang, Zhi-Liang,Wang, Xiao. "Continuous-flow step-economical synthesis of thiuram disulfidesviavisible-light photocatalytic aerobic oxidation". supporting information. p. 1280 - 1285. Retrieved 2021/02/26.
• 2、 Adeppa,Rupainwar,Misra, Krishna. "Development of an improved method for conversion of thiuram disulfides into N,N-dialkylcarbamoyl halides and derivatives". experimental part. p. 285 - 290. Retrieved 2011/03/20.