Borate(1-), tetrakis[4-(trifluoroMethyl)phenyl]-,sodiuM (1:1)

Base Information

• Chemical Name: Borate(1-), tetrakis[4-(trifluoroMethyl)phenyl]-,sodiuM (1:1)
• CAS No.: 22533-15-9
• Molecular Formula: C28H16 B F12 . Na
• Molecular Weight: 614.217
• Mol file: 22533-15-9.mol

Synonyms:Borate(1-),tetrakis(a,a,a-trifluoro-p-tolyl)-, sodium (8CI); NSC 123497; Sodium tetrakis(4-trifluoromethylphenylborate)

Chemical Property of Borate(1-), tetrakis[4-(trifluoroMethyl)phenyl]-,sodiuM (1:1)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 9.96030

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Borate(1-), tetrakis[4-(trifluoroMethyl)phenyl]-,sodiuM (1:1)

There total 2 articles about Borate(1-), tetrakis[4-(trifluoroMethyl)phenyl]-,sodiuM (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrafluoroborate (13755-29-8) + p-trifluoromethylphenyl bromide (402-43-7) + magnesium (7439-95-4) → sodium tetrakis(4-trifluoromethylphenyl)borate (22533-15-9)

Guidance literature:

With sodium hydroxide; In diethyl ether; below 25°C by the in situ method; reaction mixture is poured onto crushed ice made slightly alkaline with NaOH;

DOI:10.1016/S0003-2670(01)81750-5

Reference yield:

NH4{B(C6H4-(4)-CF3)4} (22580-12-7) + sodium methylate (124-41-4) → sodium tetrakis(4-trifluoromethylphenyl)borate (22533-15-9)

Guidance literature:

In methanol; treating ammonium salt in methanol with NaOCH3 in anhydrous CH3OH; after removal of CH3OH at 70°C under vac.; residue is dissolved in ether and passed through filled column; the ether eluate is evapd. under vac. at 80°C; dried over P4O10 under vac. at 80°C;

DOI:10.1016/S0003-2670(01)81750-5

Reference yield: 72.0%

methanol (67-56-1) + (E)-ethyl 3-((2RS,3RS)-3-methyloxiran-2-yl) acrylate (84173-36-4) + sodium tetrakis(4-trifluoromethylphenyl)borate (22533-15-9) → C9H16O4 + C15H17F3O3

Guidance literature:

With triphenyl-arsane; palladium diacetate; diisopropylamine; In 1,4-dioxane; at 110 ℃; stereoselective reaction; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1039/d0ob01226b

upstream raw materials:

sodium tetrafluoroborate

p-trifluoromethylphenyl bromide

magnesium

NH₄{B(C₆H₄-⁽⁴⁾-CF₃)4}

Downstream raw materials:

ferrocenium/tetrakis[4-(trifluoromethyl)phenyl]borate

phenyl[4-(trifluoromethyl)phenyl](trimethylsilyl)methanol

phenyl[4-(trifluoromethyl)phenyl]methanone