1H-Perfluorodecane

Base Information

• Chemical Name: 1H-Perfluorodecane
• CAS No.: 375-97-3
• Molecular Formula: C10HF21
• Molecular Weight: 520.084
• Hs Code.: 29033990
• European Community (EC) Number: 206-802-9
• DSSTox Substance ID: DTXSID60190951
• Nikkaji Number: J213.587F
• Wikidata: Q72500468
• Mol file: 375-97-3.mol

Synonyms:1H-Perfluorodecane;375-97-3;1-H-Perflurodecane;1-H-Perfluorodecane;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-Henicosafluorodecane;BRN 1810316;EINECS 206-802-9;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-Heneicosafluorodecane;Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-heneicosafluoro-;SCHEMBL61566;C10HF21;DTXSID60190951;C10-H-F21;MFCD00042110;AKOS025310204;LS-59332;FT-0607907;A823789;1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-henicosakis(fluoranyl)decane

Chemical Property of 1H-Perfluorodecane

Chemical Property:

• Vapor Pressure: 2.37mmHg at 25°C
• Melting Point: 31 °C
• Refractive Index: 1.264
• Boiling Point: 166.3 °C at 760 mmHg
• Flash Point: 60.7 °C
• PSA: 0.00000
• Density: 1.684g/cm³
• LogP: 6.89620
• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 8
• Exact Mass: 519.9742914
• Heavy Atom Count: 31
• Complexity: 650

Purity/Quality:

98%min ^*data from raw suppliers

1H-Perfluorodecane 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 1H-Perfluorodecane

There total 21 articles about 1H-Perfluorodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-Iodo-perfluorodecane (423-62-1) → α-hydroperfluorodecane (375-97-3)

Guidance literature:

With ethanol; sodium ethanolate; at 77 - 82 ℃; for 5h; Reagent/catalyst; Inert atmosphere; Large scale;

Reference yield: 91.5%

1-Iodo-perfluorodecane (423-62-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → α-hydroperfluorodecane (375-97-3) + 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Henicosafluoro-undecanal (63967-42-0) + 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Henicosafluoro-undecanoic acid dimethylamide

Guidance literature:

With lead(II) bromide; aluminium; at 40 ℃; for 2h;

DOI:10.1016/S0022-1139(00)80105-0

Reference yield: 89.0%

perfluorodecylbromide (307-43-7) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → α-hydroperfluorodecane (375-97-3) + 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Henicosafluoro-undecanal (63967-42-0) + 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Henicosafluoro-undecanoic acid dimethylamide

Guidance literature:

With lead(II) bromide; aluminium; for 3.5h; Ambient temperature;

DOI:10.1016/S0022-1139(00)80105-0

upstream raw materials:

1-chloro-10H-eicosafluoro-decane

furan

1-Iodo-perfluorodecane

thiophene

Refernces

• 1、 Cowell, Allan B.,Tamborski, Christ. "FLUOROALKYLATION OF AROMATIC COMPOUNDS". . p. 345 - 356. Retrieved 1981.
• 2、 Curran, Dennis P.,Hadida, Sabine. "Tris(2-(perfluorohexyl)ethyl)tin hydride: A new fluorous reagent for use in traditional organic synthesis and liquid phase combinatorial synthesis". . p. 2531 - 2532. Retrieved 2007/10/03.
• 3、 Hu, Chang-Ming,Tang, Xiao-Qing. "A novel synthesis of per(poly)fluoroalkyl aldehydes". . p. 217 - 222. Retrieved 2007/10/02.