Technology Process of Rhenium, tetrachlorobis(methyldiphenylphosphine)-
There total 6 articles about Rhenium, tetrachlorobis(methyldiphenylphosphine)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
hydrogenchloride; ethanol;
refluxing KReO4 with excess phosphine in EtOH/24% HCl=55:10 v/v for 15 h(pptn.); collection (filtration), washing (cold EtOH), recrystn. (CHCl3/hexane); elem. anal.;
DOI:10.1016/S0020-1693(96)05574-0
- Guidance literature:
-
In
chloroform;
ligand adding to Re complex in CHCl3, refluxing for 30 min under N2, concg. under reduced pressure, abs. EtOH adding, ppt. filtering off, washing with EtOH and hexane, drying under vacuum; identified by comparison with authentic sample;
DOI:10.1021/ic00135a068
- Guidance literature:
-
With
Cl2;
In
tetrachloromethane;
Chlorine was bubbled through a suspn. of complex in CCl4 fo 15 min;; filtered, washed with CCl4, dried in vac.;;
DOI:10.1021/ja00338a021
