Oxirane, ((4-ethenylphenoxy)methyl)-

Base Information

• Chemical Name: Oxirane, ((4-ethenylphenoxy)methyl)-
• CAS No.: 2653-39-6
• Molecular Formula: C11H12 O2
• Molecular Weight: 176.215
• DSSTox Substance ID: DTXSID40949383
• Nikkaji Number: J175.819E
• Mol file: 2653-39-6.mol

Synonyms:2653-39-6;2-[(4-ethenylphenoxy)methyl]oxirane;Oxirane, ((4-ethenylphenoxy)methyl)-;4-(Glycidyloxy)styrene;((4-Ethenylphenoxy)methyl)oxirane;Glycidyl p-vinylphenyl ether;4-Vinyl-1-phenylglycidyl ether;1,2-Epoxy-3-(p-vinylphenoxy)propane;[(4-Ethenylphenoxy)methyl]oxirane;Oxirane, [(4-ethenylphenoxy)methyl]-;p-glycidyloxystyrene;p-vinylphenyl glycidyl ether;4-Ethenylphenylglycidyl ether;SCHEMBL573151;DTXSID40949383;Propane, 1,2-epoxy-3-(p-vinylphenoxy)-;LS-101044;Propane, 1,2-epoxy-3-(p-vinylphenoxy)- (7CI,8CI)

Chemical Property of Oxirane, ((4-ethenylphenoxy)methyl)-

Chemical Property:

• Vapor Pressure: 0.00221mmHg at 25°C
• Melting Point: 30 °C
• Boiling Point: 298.8°Cat760mmHg
• Flash Point: 126.5°C
• PSA: 21.76000
• Density: 1.103g/cm³
• LogP: 2.10720
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 176.083729621
• Heavy Atom Count: 13
• Complexity: 171

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)OCC2CO2

Technology Process of Oxirane, ((4-ethenylphenoxy)methyl)-

There total 2 articles about Oxirane, ((4-ethenylphenoxy)methyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroacetonitrile (107-14-2) + 1-dodecylthiol (112-55-0) → S-dodecyl-S'-cyanomethyl trithiocarbonate (796045-97-1) + 4-vinylphenyl glycidyl ether (2653-39-6)

Guidance literature:

With carbon disulfide; sodium hydroxide; In water; isopropyl alcohol; Petroleum ether;

Reference yield:

4-Vinylphenol (2628-17-3,24979-70-2) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 4-vinylphenyl glycidyl ether (2653-39-6)

Guidance literature:

4-Vinylphenol; With sodium hydroxide; In ethanol; for 0.5h;

epichlorohydrin; In ethanol; for 12h;

DOI:10.1021/acs.macromol.5b02437

Reference yield: 87.0%

4-vinylphenyl glycidyl ether (2653-39-6) + phenylsilane (694-53-1) → C17H20O2Si

Guidance literature:

With C₁₀H₁₄CoO₅; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In tetrahydrofuran; at 20 ℃; for 3h; regioselective reaction;

DOI:10.1021/acscatal.6b02518

upstream raw materials:

chloroacetonitrile

1-dodecylthiol

4-Vinylphenol

epichlorohydrin

Refernces

• 1、 -. "METHOD FOR PREPARING GLYCIDYLOXYSTYRENE MONOMERS AND POLYMERS THEREOF". . . Retrieved 2008/12/06.