trans-Mevinphos

Base Information

• Chemical Name: trans-Mevinphos
• CAS No.: 338-45-4
• Molecular Formula: C7H13 O6 P
• Molecular Weight: 224.15
• Hs Code.: 2931900090
• European Community (EC) Number: 206-417-6,206-051-7
• UNII: 3L63962IYU
• DSSTox Substance ID: DTXSID7042481
• Nikkaji Number: J193.785E,J2.270E
• Wikidata: Q27257497
• Mol file: 338-45-4.mol

Synonyms:trans-Mevinphos;(Z)-Mevinphos;338-45-4;trans-Phosdrin;beta-Mevinphos;methyl (Z)-3-dimethoxyphosphoryloxybut-2-enoate;Mevinphos, (Z)-;EINECS 206-417-6;UNII-3L63962IYU;3L63962IYU;CROTONIC ACID, 3-HYDROXY-, METHYL ESTER, DIMETHYL PHOSPHATE, (Z)-;Methyl 3-((dimethoxyphosphinyl)oxy)isocrotonate;Mevinphos (ISO);Mevinphos [ISO];2-Butenoic acid, 3-((dimethoxyphosphinyl)oxy)-, methyl ester, (2Z)-;2-Butenoic acid, 3-((dimethoxyphosphinyl)oxy)-, methyl ester, (Z)-;Mevinphos, Inhalable;Phosdrin (Mevinphos);Mevinphos;(Phosdrin);PHD (CHRIS Code);cis-Mevinphos (old RN);(E)-Mevinphos (cis-butenoic acid);C7-H13-O6-P;2-Butenoic acid, 3-[(dimethoxyphosphinyl)oxy]-, methyl ester, (2Z)-;2-Butenoic acid, 3-[(dimethoxyphosphinyl)oxy]-, methyl ester, (Z)-;2-Carbomethoxy-1-methylvinyl dimethyl ph;Mevinphos isomer 2;MEVINPHOS, TRANS-;Methyl 3-((dimethoxyphosphinyl)oxy)-2-butenoate (9CI);Methyl 3-hydroxycrotonate dimethyl phosphate ester (8CI);SCHEMBL3429514;DTXSID7042481;GEPDYQSQVLXLEU-WAYWQWQTSA-N;(Z)-Mevinphos (trans-butenoic acid);CIS-MEVINPHOS PESTANAL 50 MG;CIS-MEVINPHOS PESTANAL 50 MG;LS-55589;methyl 3-(dimethoxyphosphinyloxy)-crotonate;Methyl 3-[(dimethoxyphosphinyl)oxy]crotonate;W-109521;Q27257497

Chemical Property of trans-Mevinphos

Chemical Property:

• PSA: 80.87000
• LogP: 1.48070
• Storage Temp.: 2-8°C
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 224.04497513
• Heavy Atom Count: 14
• Complexity: 263

Purity/Quality:

98%min ^*data from raw suppliers

trans-Mevinphos solution 100μg/mL in acetonitrile, PESTANAL ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn,N,T+
• Hazard Codes: F,Xn,N,T+
• Statements: 11-20/21/22-36-50/53-27/28
• Safety Statements: 16-36/37-61-60-45-28-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CC(=O)OC)OP(=O)(OC)OC
• Isomeric SMILES: C/C(=C/C(=O)OC)/OP(=O)(OC)OC

Technology Process of trans-Mevinphos

There total 2 articles about trans-Mevinphos which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2-chloroacetoacetate (4755-81-1,935731-92-3) + phosphorous acid trimethyl ester (121-45-9) → (E)-mevinphos (298-01-1) + dimethyl 2-carbomethoxy-1-methylvinyl phosphate (338-45-4)

Guidance literature:

Reference yield:

→ dimethyl 2-carbomethoxy-1-methylvinyl phosphate (338-45-4)

Guidance literature:

(techn.);

DOI:10.1021/jo01068a077

Reference yield:

dimethyl 2-carbomethoxy-1-methylvinyl phosphate (338-45-4) → dimethylphosphoric acid (813-78-5) + 3-(hydroxy-methoxy-phosphoryloxy)-trans-crotonic acid methyl ester (15461-33-3)

Guidance literature:

at 30 ℃; Zeitlicher Verlauf bei pH 11;

upstream raw materials:

methyl 2-chloroacetoacetate

phosphorous acid trimethyl ester

Downstream raw materials:

dimethylphosphoric acid

3-(hydroxy-methoxy-phosphoryloxy)-trans-crotonic acid methyl ester