Triiodo(trifluoromethyl)germane

Base Information

• Chemical Name: Triiodo(trifluoromethyl)germane
• CAS No.: 1512-08-9
• Molecular Formula: CF3GeI3
• Molecular Weight: 522.31
• DSSTox Substance ID: DTXSID10542729
• Wikidata: Q82419479
• Mol file: 1512-08-9.mol

Synonyms:triiodo(trifluoromethyl)germane;1512-08-9;TRIFLUOROMETHYLTRIIODOGERMANE;SCHEMBL15664480;DTXSID10542729;LRIZKSDJWVSDFZ-UHFFFAOYSA-N

Chemical Property of Triiodo(trifluoromethyl)germane

Chemical Property:

• Refractive Index: 1.6571
• Boiling Point: 42oC 0mm
• PSA: 0.00000
• LogP: 3.75170
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 523.6298
• Heavy Atom Count: 8
• Complexity: 81.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)[Ge](I)(I)I

Technology Process of Triiodo(trifluoromethyl)germane

There total 7 articles about Triiodo(trifluoromethyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

germanium tetraiodide (13450-95-8) + bis(trifluoromethyl)mercury (371-76-6) → perfluormethylgermanium iodide (1512-08-9) + perfluormethylgermanium iodide (754-36-9)

Guidance literature:

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.55;

DOI:10.1021/ja00474a013

Reference yield: 53.0%

germanium tetraiodide (13450-95-8) + bis(trifluoromethyl)mercury (371-76-6) → perfluormethylgermanium iodide (1512-08-9) + perfluormethylgermanium iodide (754-36-9) + tris(trifluoromethyl)germyl iodide (66348-18-3)

Guidance literature:

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.98;

DOI:10.1021/ja00474a013

Reference yield: 35.0%

trifluoromethylgermane (85906-84-9) → (CF3)GeH2(C2H5) (104209-07-6) + (CF3)GeH(C2H5)2 (104209-08-7) + perfluormethylgermanium iodide (1512-08-9)

Guidance literature:

With diethyl zinc; C₂H₅I; In neat (no solvent); byproducts: C2H6, CH4; (C2H5)2Zn and slight excess C2H5I condensed with CF3GeH3, mixt. warmed to room temp.; fractional condensation of volatile materials;

DOI:10.1016/0022-328X(86)84031-1

upstream raw materials:

iodotrifluoromethane

germanium tetraiodide

bis(trifluoromethyl)mercury

trifluoromethylgermane

Downstream raw materials:

trifluoromethan

germanium tetraiodide

germanium tetrafluoride

(trifluoro methyl) trichloro germane

Refernces

• 1、 Eujen, R.,Mellies, R.,Petrauskas, E.. "(TRIFLUOROMETHYL)GERMANES. PREPARATION AND PROPERTIES OF (CF3)2GeHX (X = H, D, F, Cl, Br, I, CH3) AND CF3GeHnX3-n (X = H, D, CF2H, CH3)". . p. 29 - 40. Retrieved 2007/10/02.