Ditridecylamine

Base Information

• Chemical Name: Ditridecylamine
• CAS No.: 5910-75-8
• Molecular Formula: C26H55 N
• Molecular Weight: 381.729
• European Community (EC) Number: 227-624-8,309-798-8
• NSC Number: 157590
• DSSTox Substance ID: DTXSID4064056
• Nikkaji Number: J42.962G
• Wikidata: Q26840868
• Mol file: 5910-75-8.mol

Synonyms:DITRIDECYLAMINE;N-Tridecyltridecan-1-amine;101012-97-9;1-Tridecanamine, N-tridecyl-;5910-75-8;Bis(tridecyl)amine;Di-n-tridecylamine;Ditridecyl amine;Di(tridecyl)amine;HOE-F 2562;EINECS 227-624-8;N-Tridecyl-1-tridecanamine;NSC 157590;BRN 1783160;ditridecylamin;Ditrurocilamina;di-tridecylamine;Di-n-trurocilamina;SCHEMBL186134;1-Tridecanamina, N-tridecil-;N-Tridecyl-1-tridecanamine #;Ditridecylamine (6CI7CI8CI);DTXSID4064056;WLN: 13M13;N(CCCCCCCCCCCCC)CCCCCCCCCCCCC;EINECS 309-798-8;MFCD00026595;NSC157590;AKOS015915173;NSC-157590;LS-63348;FT-0655518;EC 309-798-8;F81297;N-Tridecyl-tridecanamine (mixtures of isomeres);A800313;Q26840868

Chemical Property of Ditridecylamine

Chemical Property:

• Vapor Pressure: 1.04E-08mmHg at 25°C
• Melting Point: 56.5°C
• Refractive Index: 1.4679 (estimate)
• Boiling Point: 461.8°Cat760mmHg
• Flash Point: 162.9°C
• PSA: 12.03000
• Density: 0.818g/cm³
• LogP: 9.58890
• XLogP3: 12
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 24
• Exact Mass: 381.433450759
• Heavy Atom Count: 27
• Complexity: 214

Purity/Quality:

99%, ^*data from raw suppliers

DITRIDECYL AMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCCCCCCCCCNCCCCCCCCCCCCC

Technology Process of Ditridecylamine

There total 5 articles about Ditridecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) + carbon monoxide (201230-82-2) + benzylamine (100-46-9) → 1-tridecanamine (2869-34-3) + N,N-dimethyldodecyl amine (5910-75-8)

Guidance literature:

1-dodecene; carbon monoxide; benzylamine; With C₂₀H₂₂N₂ORh⁽¹⁺⁾*C₂₄H₂₀B^(1-); hydrogen; In toluene; at 85 ℃; for 6h; under 37503.8 Torr;

With palladium 10% on activated carbon; hydrogen; In ethanol; at 75 ℃; for 24h; under 3750.38 Torr;

DOI:10.1016/j.tetlet.2021.153018

Reference yield:

1-tridecanamine (2869-34-3) → N,N-dimethyldodecyl amine (5910-75-8)

Guidance literature:

With nickel; at 200 ℃;

DOI:10.1021/jo01184a011

Reference yield:

N,N-bis(tridecyl)trifluoromethanesulfonamide → N,N-dimethyldodecyl amine (5910-75-8)

Guidance literature:

With lithium aluminium tetrahydride; In 1,4-dioxane; Heating;

DOI:10.1016/j.jfluchem.2005.08.012

upstream raw materials:

1-tridecanamine

tridecanenitrile

tridecan-1-ol

1-dodecene

Refernces

• 1、 October, Jacquin,Mapolie, Selwyn F.. "Sequential hydroaminomethylation/Pd-catalyzed hydrogenolysis as an atom efficient route to valuable primary and secondary amines". supporting information. . Retrieved 2021/04/12.