2-trimethylsilyl-1-propanol

Base Information

• Chemical Name: 2-trimethylsilyl-1-propanol
• CAS No.: 145428-83-7
• Molecular Formula: C₆H₁₆OSi
• Molecular Weight: 132.278
• Mol file: 145428-83-7.mol

Synonyms:1-Propanol,2-(trimethylsilyl)-, (?à)-; (?à)-2-Trimethylsilyl-1-propanol;2-Trimethylsilyl-1-propanol

Chemical Property of 2-trimethylsilyl-1-propanol

Chemical Property:

• Vapor Pressure: 0.747mmHg at 25°C
• Boiling Point: 162.4°Cat760mmHg
• Flash Point: 53°C
• PSA: 20.23000
• Density: 0.82g/cm³
• LogP: 1.70700

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-trimethylsilyl-1-propanol

There total 3 articles about 2-trimethylsilyl-1-propanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(trimethylsilyl)propene (18163-07-0) → dimethyl(trimethylsilyl)methyl alcohol (40965-54-6) + 2-(trimethylsilyl)-1-propanol (145428-83-7,145428-86-0,145428-87-1)

Guidance literature:

With borane-THF; Yield given. Multistep reaction; 1) 0 deg C, 2) 30 percent H₂O₂, 3 N NaOH;

DOI:10.1021/jo01306a006

Reference yield:

9-(2-Trimethylsilanyl-propyl)-9-bora-bicyclo[3.3.1]nonane (72610-07-2) → 2-(trimethylsilyl)-1-propanol (145428-83-7,145428-86-0,145428-87-1)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; for 1h; Yield given; Heating;

DOI:10.1021/jo01306a006

Reference yield:

→ 2-(trimethylsilyl)-1-propanol (145428-83-7,145428-86-0,145428-87-1)

Guidance literature:

upstream raw materials:

2-(trimethylsilyl)propene

9-(2-Trimethylsilanyl-propyl)-9-bora-bicyclo[3.3.1]nonane

Refernces

• 1、 Soderquist, John A.,Brown, Herbert C.. "Hydroboration. 56. Convenient and Regiospecific Route to Functionalized Organosilanes through the Hydroboration of Alkenylsilanes.". . p. 3571 - 3578. Retrieved 2007/10/02.