4-Methoxyphenanthrene

Base Information

• Chemical Name: 4-Methoxyphenanthrene
• CAS No.: 15638-06-9
• Molecular Formula: C15H12O
• Molecular Weight: 208.26
• Hs Code.: 2909309090
• Mol file: 15638-06-9.mol

Synonyms:methyl-[4]phenanthryl ether;Methyl-[4]phenanthryl-aether;4-Methoxyphenanthren;Phenanthrene, 4-methoxy-;4-methoxy-phenanthrene;Phenanthrene,4-methoxy;

Chemical Property of 4-Methoxyphenanthrene

Chemical Property:

• Melting Point: 64.5-66 °C
• Boiling Point: 375.5±11.0 °C(Predicted)
• PSA: 9.23000
• Density: 1.146±0.06 g/cm3(Predicted)
• LogP: 4.00160

Purity/Quality:

4-METHOXYPHENANTHRENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Methoxyphenanthrene

There total 28 articles about 4-Methoxyphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C29H28N4O5S2 (1392144-19-2) → 4-methoxyphenanthren (15638-06-9)

Guidance literature:

With dirhodium tetraacetate; lithium tert-butoxide; In toluene; at 90 ℃; for 1h; Inert atmosphere; Molecular sieve;

DOI:10.1002/anie.201201374

Reference yield: 93.0%

5-methoxyphenanthren-9-yl trifluoromethanesulfonate (141807-43-4) → 4-methoxyphenanthren (15638-06-9)

Guidance literature:

With palladium diacetate; formic acid; triphenylphosphine; In N,N-dimethyl-formamide; at 60 - 70 ℃;

DOI:10.1139/v00-055

Reference yield: 80.0%

2-(2-methoxyphenyl)cinnamaldehyde → 4-methoxyphenanthren (15638-06-9)

Guidance literature:

With dipotassium peroxodisulfate; sodium triflate; silver nitrate; In acetonitrile; at 90 ℃; for 24h; Reagent/catalyst;

upstream raw materials:

4-methoxy-phenanthrene-9-carboxylic acid

4-phenanthryl acetate

dimethyl sulfate

o-Amino-m'-methoxy-cis-stilben

Downstream raw materials:

4-phenanthrol

5-methoxychryzene

Refernces

• 1、 Full, Julian,Panchal, Santosh P.,G?tz, Julian,Krause, Ana-Maria,Nowak-Król, Agnieszka. "Modular Synthesis of Organoboron Helically Chiral Compounds: Cutouts from Extended Helices". supporting information. p. 4350 - 4357. Retrieved 2021/01/29.
• 2、 Yamamoto, Yoshihiko,Matsui, Kazuma,Shibuya, Masatoshi. "A combined experimental and computational study on the cycloisomerization of 2-ethynylbiaryls catalyzed by dicationic arene ruthenium complexes". supporting information. p. 7245 - 7255. Retrieved 2015/05/05.